Given the series, one method of determining the function the series sums to is to derive a differential equation. In this case, given that f(x)= \sum_{n=0}^\infty x^n/n! we can see that this series is convergent for all x. In particular, then, it is uniformly convergent for any closed and bounded interval and so differentiable, term by term, for any x.
That is, for any x, f'(x)= \sum_{n=0}^\infty nx^{n-1}/n!= \sum_{n=1}^\infty x^{n-1}/(n-1)!
Letting j= n-1, that is \sum_{j=0} x^j/j!= f(x). So f(x) satisfies the differential equation f'(x)= f(x) and it is easy to show that any solution of that differential equation is of the form Ce^x for some constant C. And since f(0)= 1+ 0+ 0+ ...= 1, C= 1 and \sum_{n=0}^\infty x^n/n!= e^x
(By the way, what you wrote, f(x)= 1+ x+ x^2/2!+ \cdot\cdot\cdot+ x^n/n! is NOT the infinite sum and is a polynomial.)