Detecting Enantiomeric Excess in a 400MHz 1H NMR Instrument

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Detecting enantiomeric excess using 1H NMR on a 400 MHz instrument without chiral agents is not feasible, as enantiomers exhibit identical NMR spectra in achiral environments. This means that without the introduction of a chiral agent, it is impossible to differentiate between the two enantiomers based solely on their NMR signals.
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is it possible to detect the presence of enantiomeric exess of one enantiomer over the other using 1H nmr in a 400 mhz instrument without the use of any chiral agent?
 
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Is it possible to detect the presence of enantiomeric exess of one enantiomer over the other in a chiral compound by using 1H nmr analysis using a 400 mhz instrument without the use of any chiral agent?
 
No, enantiomers should have identical NMR spectra in an achiral environment.
 
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert? What is so special with a full p orbital? Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive. Can someone explain it to me? Thanks!!
It seems like a simple enough question: what is the solubility of epsom salt in water at 20°C? A graph or table showing how it varies with temperature would be a bonus. But upon searching the internet I have been unable to determine this with confidence. Wikipedia gives the value of 113g/100ml. But other sources disagree and I can't find a definitive source for the information. I even asked chatgpt but it couldn't be sure either. I thought, naively, that this would be easy to look up without...

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