I would like to add to the above because the concepts in this problem aren't always explained clearly in the E&M textbooks for what they represent. ## \\ ## The basic equation for the electric field is ## \nabla \cdot E=\rho_{total}/\epsilon_o ## where ## \rho_{total} ## is the total charge density. Meanwhile for linear dielectrics ## P=\chi E ## where ## \chi ## is the dielectric susceptibility. A polarization charge density results when there are gradients in the polarization vector ## P ##, i.e. any time that the polarization ## P ## is non-uniform. The polarization charge density is given by ## \rho_p=-\nabla \cdot P ##. (If a material has uniform polarization ## P ##, the result is a discontinuity in ## P ## at the surface boundary. The surface charge density ## \sigma_p=\hat{n} \cdot P ## can readily be found by using Gauss law on the equation ## -\nabla \cdot P=\rho_p ## around the surface boundary.) ## \\ ## Now going back to the equation ## \nabla \cdot E=\rho_{total}/\epsilon_o ##, we can make a mathematical construction ## D=\epsilon_o E+P ## and take the divergence of both sides of this equation: ## \nabla \cdot D=\epsilon_o \nabla \cdot E +\nabla \cdot P ##. The result is ## \nabla \cdot D=\rho_{total}-\rho_p ##. Since ## \rho_{total}= \rho_{free}+\rho_p ## the result is ## \nabla \cdot D=\rho_{free} ## where ## D ## is the mathematical construction defined by ## D=\epsilon_o E+P ##. (Note: the vector symbol has been left off of ## D, \, E, \, and \, P ## in all of this for brevity). The ## D ## formalism makes for a handy way of solving these problems, but the problem can be solved using just the ## E ## and ## P ## and the ## \chi ## as follows: ## \\ ## ## P=\chi E_i ## and let's assume uniform ## P ## and ## E_i ##. ## \sigma_p=\hat{n} \cdot E_i ## as previously mentioned. The result is a ## \sigma_p=P ## on one surface and ## \sigma_p=-P ## on the other. (Here ## P ## is just the amplitude of vector ## P ##. ) The electric field in the material from these two layers of surface polarization charge is given by ## E_p=-P/\epsilon_o ##. Now ## E_i=E_o+E_p ## where ## E_o ## is the applied field. We can substitute for ## E_i=P/\chi ## , so that ## P/\chi=E_o-P/\epsilon_o ##. Solving, we get ## P=\epsilon_o E_o/(1+\epsilon_o/\chi ) ##. Since ## P=\chi E ## and ## D=\epsilon_o E+P ##, we get ## D=(\epsilon_o+\chi) E =\epsilon \epsilon_o E ##. This makes ## \epsilon=1+\chi/\epsilon_o ##. Putting in just the amplitude of ## E_o ## and ## P ##, since ## P=\sigma_p ##, a little algebra where we substitute for ## \chi ## in terms of ## \epsilon ## gives: ## \\ ## ## \sigma_p=\epsilon_o E_o (1-1/\epsilon ) ##. ## \\ ## This solution took more effort than simply using the mathematical construction ## D ## along with the equations that apply for it, but I wanted to show that the same result can be obtained in a more fundamental way, (without using the ## D ##), by working with just the ## E ## and ## P ## and ## \chi ##.