The Brewster angle phenomenon occurs when the electric field vector lies in the plane of incidence, allowing for no reflection due to balanced tangential fields at the interface. This balance is achieved through geometric projection in air and a reduced electric field in the dielectric, eliminating the need for a reflected wave. In contrast, when the magnetic field vector is in the plane of incidence, the electric field does not experience geometric reduction, necessitating reflection to maintain field balance. Reflection at the interface is determined by impedance mismatches, and at the Brewster angle, the impedance can be balanced with just incident and transmitted waves. Thus, the Brewster angle is a unique case where reflection is absent due to specific conditions of electric and magnetic field alignment.