Do Ideal Gases Absorb Heat When Expanded?

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Discussion Overview

The discussion centers around whether ideal gases absorb heat when they expand, exploring various scenarios and processes involved in gas expansion, including adiabatic and isothermal processes. Participants express differing views on the conditions under which heat absorption occurs, as well as the implications of ideal gas behavior.

Discussion Character

  • Debate/contested
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • Some participants suggest that ideal gases do absorb heat during expansion, particularly in isothermal processes.
  • Others argue that ideal gases do not necessarily absorb heat when they expand, especially during adiabatic expansion where no heat exchange occurs with the surroundings.
  • It is noted that the process of expansion affects whether heat is absorbed; for instance, expanding through a throttling valve may not involve heat absorption.
  • Some participants mention that the temperature of an ideal gas does not change during free expansion, implying no heat absorption occurs in that case.
  • There is a discussion about the relationship between internal energy, work done by the gas, and heat flow, referencing the first law of thermodynamics.
  • Questions are raised about the conditions under which heat absorption occurs, particularly in high-pressure containers and the specifics of applying heat to the gas.

Areas of Agreement / Disagreement

Participants do not reach a consensus on whether ideal gases absorb heat during expansion, with multiple competing views remaining on the conditions and processes involved.

Contextual Notes

The discussion highlights the complexity of gas behavior under different conditions, including the need to consider specific processes and the implications of the first law of thermodynamics. There are unresolved questions regarding the extent of heat absorption and the definitions of various processes.

s.p.q.r
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Hi,

Do IDEAL gases absorb heat when they expand? I asked a few people this question, half said yes and half said no.

Im after a simple yes or no answer with a small explanation to clarify this one.

If anyone knows, please reply.

Cheers!

:smile:
 
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Geez, I sure would have thought so ... how else would their temperatures rise? What was the argument against this?

- Bruce
 
The arguments against are-

-gasses expand because of the heat applied but don't actually take in any heat from around them. the heat/energy increases the activity between the atom not within the atom

-While gasses can take in heat while they are expanding, an expanding gas does not necessarily need to take in heat. For example, during an adiabatic expansion, the gas expands without exchanging heat with its surroundings. The temperature of the gas decreases because its internal energy supplies the work necessary for the gas to expand.

Sounds correct to me. But, my 1st thought was that ideal gases do absorb heat. This is a harder question then I thought.

Anyone else have an idea?
 
s.p.q.r said:
The arguments against are-

-gasses expand because of the heat applied but don't actually take in any heat from around them. the heat/energy increases the activity between the atom not within the atom
What does "activity between the atom(s)" mean? It sounds like more kinetic energy, which means more heat.

s.p.q.r said:
-While gasses can take in heat while they are expanding, an expanding gas does not necessarily need to take in heat. For example, during an adiabatic expansion, the gas expands without exchanging heat with its surroundings. The temperature of the gas decreases because its internal energy supplies the work necessary for the gas to expand.

Sounds correct to me. But, my 1st thought was that ideal gases do absorb heat. This is a harder question then I thought.

Anyone else have an idea?
Yes, during adiabatic expansion that's true, but of course, not all expansion is adiabatic. Am I not understanding the question correctly? :confused:
 
You can make a gas absorb heat or not. It is all a matter of the process. If, for example, you expand a gas through a throttling valve and the valve and pipes are insulated, the gas will expand and cool and not absorb heat. If, for example, you take a non-rigid container of a gas and apply heat to it, the gas will absorb heat and expand.
 
Free expansion, no heat; make it work to expand, and it absorbs heat --- part of the definition of an "ideal gas."
 
ideal gases can expand isothermally so I would assume they could absorb heat.

Anyway ideal gases were meant to be a simple model of a gas that accurately reflects reality as far as it can; it's a pretty rubbish model if it forbids isothermal expansions :s
 
Just some guy said:
ideal gases can expand isothermally so I would assume they could absorb heat.

Anyway ideal gases were meant to be a simple model of a gas that accurately reflects reality as far as it can; it's a pretty rubbish model if it forbids isothermal expansions :s

How does free expansion forbid isothermal expansion?
 
Thank you all for your help. Much appreciated. I am interested in the reply of russ_watters.

russ_watters said:
You can make a gas absorb heat or not. It is all a matter of the process. If, for example, you expand a gas through a throttling valve and the valve and pipes are insulated, the gas will expand and cool and not absorb heat. If, for example, you take a non-rigid container of a gas and apply heat to it, the gas will absorb heat and expand.

So, they won't absorb heat through a throttling valve. (I think I know what that is)
Will the ideal gases absorb heat if they were in a high pressure container?

Thanks Again.:rolleyes:
 
  • #10
Bystander said:
How does free expansion forbid isothermal expansion?

I never said it did :/
 
  • #11
s.p.q.r said:
So, they won't absorb heat through a throttling valve. (I think I know what that is)
Bottom of the page (you may as well read the whole page...): http://en.wikibooks.org/wiki/Engineering_Thermodynamics/First_Law
Will the ideal gases absorb heat if they were in a high pressure container?
If you don't apply heat to it, it won't absorb heat.
 
Last edited:
  • #12
"If you don't apply heat to it, it won't absorb heat"

What if I did apply heat to it? Will it absorb this heat? If so, to what extent?

Pls get back.

Cheers.
 
  • #13
Ideal gases when they expand ( when you allow them to fill a bigger
volume ) don't absorb heat ( don't change their temperature ).

Real gases do, because their molecules are attracted between them.

In ideal gases its supposed the molecules don't feel any attraccion.
 
  • #14
s.p.q.r said:
Thank you all for your help. Much appreciated. I am interested in the reply of russ_watters.
So, they won't absorb heat through a throttling valve. (I think I know what that is)
Will the ideal gases absorb heat if they were in a high pressure container?
There is no correct answer your question. It is like asking whether a car gains energy when it goes down the road.

You have to apply the first law of thermodynamics to any situation.

\Delta Q = \Delta U + \Delta W

where \Delta W is the work done by the gas. If in any process, \Delta Q > 0 then there is a heat flow into the gas. If \Delta Q < 0 then there is a heat flow out of the gas.

If the gas expands, the gas does work, so \Delta W > 0. But that does not tell you if heat flows into the gas. You have to know the change in temperature of the gas in this process. If it does not change temperature (\Delta U = 0) then Q is positive. If it loses internal energy in an amount that is less than the work done, Q is positive. If it loses more internal energy than the work done, then Q is negative. etc.

AM
 
  • #15
s.p.q.r said:
"If you don't apply heat to it, it won't absorb heat"

What if I did apply heat to it? Will it absorb this heat? If so, to what extent?

Pls get back.

Cheers.
As I said in my first post, it is all a matter of the process. If you apply heat, it will absorb heat, but the particulars depend on the process.
 

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