Drawing a Lewis Dot Structure for Octathiocane (S8)

AI Thread Summary
To draw a Lewis dot structure for octathiocane (S8), it's essential to create a non-cyclic, net neutral molecule that adheres to the octet rule. Initial attempts at a straight chain resulted in terminal sulfurs carrying a negative charge, leading to an overall negative charge. Adjusting electron pairs resolved the charge issue but caused a violation of the octet rule for an adjacent sulfur. The solution involves balancing formal charges while ensuring that sulfur atoms can convert lone pairs into bonding pairs. Ultimately, achieving a stable structure requires careful consideration of charge distribution and octet fulfillment.
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Homework Statement


How can I draw a Lewis dot structure for octathiocane (S8) which is non-cyclic, net neutral, and which does not violate the octet rule?


Homework Equations


None.


The Attempt at a Solution


First, I tried drawing a straight chain molecule, but the two terminal sulfurs each have a negative charge, giving a net negative charge overall.

I then tried pushing an electron pair from one of the terminal sulfurs inwards, which solves the charge issue but makes the penultimate sulfur on one side violate the octet rule...

I'm stumped. Any advice?
 
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- It is a straight chain.
- One end has a 1- formal charge, the other has a 0 formal charge. (Net charge=0)
- Sulfur can change lone pairs to bonds.

You should be able to figure it out with this, if not let me know. :D
 
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