Effect of ph on uv absorbance of benzoic acid

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The discussion centers on the UV absorbance properties of benzoate ions compared to benzoic acid. It highlights that while phenoxide ions and aniline absorb UV radiation at longer wavelengths and with greater efficiency than their protonated forms, benzoate ions reportedly absorb at shorter wavelengths and with less efficiency than benzoic acid, as indicated by a referenced source. The inquiry seeks clarification on this observation and questions the accuracy of the source, particularly regarding the behavior of dimers of benzoic acid at varying pH levels. The conversation emphasizes the need for further understanding of these UV absorbance differences and their implications in chemical behavior.
jethro
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i was recently reading about uv absorbance, and i understand why species such as the phenoxide ion and aniline absorb uv radiation at longer radiation and with more efficiency than their protonated counterparts.
i have spent long hours, however, trying to figure out why a benzoate ion might absorb at a shorter wavelength, and with less efficiency, than benzoic acid.
i have attached the source which suggests that this is true; there is a graph on page 5. my last resort is to say that the source is wrong but i want to make sure... can anyone help?
 

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Chemistry news on Phys.org
How might dimers of benzoic acid be different at high pH vs. low pH?

http://pubs.acs.org/doi/abs/10.1021/ja00503a016"
 
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of course!

...much appreciated, thank you.
 
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