Effect of ph on uv absorbance of benzoic acid

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SUMMARY

The discussion centers on the effect of pH on the UV absorbance of benzoic acid and its ionized form, the benzoate ion. It is established that the phenoxide ion and aniline absorb UV radiation more efficiently at longer wavelengths compared to their protonated forms. The inquiry specifically addresses why the benzoate ion absorbs at shorter wavelengths and with less efficiency than benzoic acid, referencing a source that supports this claim. The discussion also raises questions about the behavior of benzoic acid dimers at varying pH levels.

PREREQUISITES
  • Understanding of UV absorbance principles
  • Knowledge of benzoic acid and its ionization
  • Familiarity with pH effects on chemical species
  • Ability to interpret scientific graphs and data
NEXT STEPS
  • Research the UV absorbance characteristics of benzoic acid and benzoate ions
  • Investigate the impact of pH on dimer formation of benzoic acid
  • Explore the differences in UV absorbance between protonated and deprotonated species
  • Examine relevant literature on UV-Vis spectroscopy techniques
USEFUL FOR

Chemists, researchers in organic chemistry, and students studying UV absorbance and pH effects on chemical species will benefit from this discussion.

jethro
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i was recently reading about uv absorbance, and i understand why species such as the phenoxide ion and aniline absorb uv radiation at longer radiation and with more efficiency than their protonated counterparts.
i have spent long hours, however, trying to figure out why a benzoate ion might absorb at a shorter wavelength, and with less efficiency, than benzoic acid.
i have attached the source which suggests that this is true; there is a graph on page 5. my last resort is to say that the source is wrong but i want to make sure... can anyone help?
 

Attachments

Chemistry news on Phys.org
How might dimers of benzoic acid be different at high pH vs. low pH?

http://pubs.acs.org/doi/abs/10.1021/ja00503a016"
 
Last edited by a moderator:
of course!

...much appreciated, thank you.
 

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