Einstein's theory for specific heat

Titan97
Gold Member
Messages
450
Reaction score
18
I have uploaded a page from my prof's lecture on specific heat.

Its given that average energy for each vibrational mode is $$\frac{h\nu}{e^{\frac{h\nu}{T}}-1}$$

Hence $$U=(\text{number of vibrational modes)}\times\frac{h\nu}{e^{\frac{h\nu}{T}}-1}$$

In the lecture slide, the number of vibrational mode is 3N. Is this for a monoatomic structure? Because it doesn't consider rotational degree of freedom.
 

Attachments

on Phys.org
There is no rotational mode in Einstein's model.
He models the crystal as a collection of uncoupled harmonic oscillators, all oscillating with the same frequency.

And if we switch to more realistic models like Debye's or to experimental results, the specific heat of solids around room temperature is due to lattice vibrations only.
 
  • Like
Likes   Reactions: Titan97

Similar threads

  • · Replies 70 ·
3
Replies
70
Views
10K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 6 ·
Replies
6
Views
14K
  • · Replies 5 ·
Replies
5
Views
9K
  • · Replies 7 ·
Replies
7
Views
2K
  • · Replies 5 ·
Replies
5
Views
3K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 2 ·
Replies
2
Views
7K
  • · Replies 10 ·
Replies
10
Views
7K
  • · Replies 2 ·
Replies
2
Views
1K