Find pH at Endpoint: Formic Acid Titration with NaOH Solution - 8.32 Answer

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In summary, the endpoint of the titration between 10 mL of a solution of formic acid HCOOH and .1034 M NaOH was determined to be at pH 8.32. The calculation involves treating the solution as a weak base of HCOO- and using the equation Kw/Kb = ([OH-](Facid + [OH-])/(Fsalt - [OH-]) to determine the concentration of hydroxide ions at the equivalence point. This value is then converted to pH to determine the endpoint.
  • #1
coookiemonste
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Homework Statement


10 mL of a solution of formic acid HCOOH required 31.23 mL of .1034 M NaOH to titrate it. Find the pH at the endpoint. Answer is 8.32.


Homework Equations



pH=pKa + log[A-]/[HA]

The Attempt at a Solution


initial concentration of HCOOH is .3229 M from fact .1034 M(.03123L)=.003229 mol NaOH, .003229mol HCOOH/.01L =concentration of HCOOH.
pka= 3.75
 
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  • #2
A different viewpoint can be more helpful, starting with the salt as a base (opposite of "acid").

Ka*Kb=Kw, reaction being H2O + NaA <--------> Na+ + OH- + HA
but you only care about H2O + A- <------> OH- + HA.

Kw/Kb = ([OH-](Facid + [OH-])/(Fsalt - [OH-]) = [OH-][HA]/[A-]

(please make your own adjustments for my bad typesetting, or lack of good typesetting).

From the "K" line, you really want to focus on: Kw/Kb = ([OH-](Facid + [OH-])/(Fsalt - [OH-])

Facid means the formal concentration of the weak acid, which is extremely small at the endpoint.
Fsalt means the formal concentration of the sodium formate, as if the titration solution were prepared only from this salt alone without use of acid or base.
 
  • #3
At the equivalence point (which is what you can calculate, end point is when you have detected titration should stop) you have a solution of formate, so you just calculate pH of salt. That means - as symbolipoint suggested - treating solution as solution of a weak base HCOO- and calculating [OH-], then converting it to pH.

Much more here:

acid base titration equivalence point calculation

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1. What is Endpoint Titration?

Endpoint titration is a laboratory technique used to determine the concentration of a substance in a solution by adding a reagent of known concentration until the reaction reaches a definite endpoint. The endpoint is when the reaction is complete, and the solution has reached a specific color change or pH level. This allows for the calculation of the unknown concentration based on the known concentration and volume of the reagent used.

2. What are the different types of Endpoint Titration?

There are several types of endpoint titration, including acid-base titration, redox titration, complexometric titration, and precipitation titration. Each type uses a different type of reaction and indicator to reach the endpoint.

3. What is an indicator in Endpoint Titration?

An indicator is a substance that changes color when the endpoint of a titration is reached. It is added to the solution being titrated and helps the scientist determine when the reaction is complete. Different indicators are used for different types of titrations.

4. What are the sources of error in Endpoint Titration?

The main sources of error in endpoint titration include inaccurate measurements of reagents, not adding enough indicator, incomplete reactions, and human error in reading the endpoint. It is essential to use precise and calibrated equipment and follow proper techniques to minimize errors.

5. What are the applications of Endpoint Titration?

Endpoint titration has various applications in the scientific field, including determining the concentration of acids and bases in a solution, analyzing water quality, and measuring the purity of chemicals. It is also used in pharmaceuticals to determine the concentration of active ingredients in medications.

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