Equal electronegativities and covalent bond formation

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When two atoms have equal electronegativities, they form covalent bonds, but they do not create polar covalent bonds. The statement in question is false because it specifies "polar" covalent bonds, which require a difference in electronegativity. The discussion highlights that while the initial premise may hold true for two atoms, exceptions arise in more complex interactions. An example provided is Gamma-boron, where differing electronegativities in clusters lead to partial ionic characteristics. Thus, the key takeaway is that equal electronegativities do not guarantee polar covalent bond formation.
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Homework Statement


True or false: When two atoms are equally electronegative, they will interact to form polar covalent bonds.

Homework Equations


Atoms with similar or equal electronegativities share electrons between them and are connected by covalent bonds.
Atoms with large differences in electronegativity transfer electrons to form ions. The ions then are attracted to each other, = an ionic bond.

The Attempt at a Solution


I answered true and it was marked wrong. Not understanding why though. The only thing I can think of is maybe the question is asking if two atoms of equal electronegativity will necessarily form covalent bond. Other than that, I thought it should be true. Not sure what I did wrong. thanks
 
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this is stupid. I just noticed it says "polar" covalent. That must be the problem!
 
sp3sp2sp said:
this is stupid. I just noticed it says "polar" covalent. That must be the problem!
Yes, it is the qualifier "polar" that makes the statement false.
 
Just wanted to note that, while this statement is probably true for the interaction of only two atoms, there are counterexamples when more than two are involved.
For example, there exists a partially ionic modification of boron (Gamma-boron) consisting of B2+ and B12- clusters arranged in a NaCl type lattice.
 
Isn't that simply because the electronegativities of the pseudoatoms B2+ and B12- are not the same though, at some level?
 

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