Excitation by photons smaller than energy interval

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SUMMARY

The discussion centers on time-dependent perturbation theory and its implications for energy conservation during photon absorption events. Specifically, it addresses the transition probability formula P_{a \rightarrow b}=\frac{sin^{2}[(\omega_{0}-\omega)t/2]}{(\omega_{0}-\omega)^2}, which indicates that transitions can occur even when the photon energy is less than the energy difference between states. The apparent nonconservation of energy is clarified through Messiah's text, emphasizing that it is the unperturbed energy that is not conserved, rather than the total energy of the system, which includes the perturbation.

PREREQUISITES
  • Understanding of time-dependent perturbation theory
  • Familiarity with quantum mechanics terminology
  • Knowledge of energy conservation principles in quantum systems
  • Access to Messiah's quantum mechanics textbook, particularly Volume 1
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  • Study the implications of time-dependent perturbation theory in quantum mechanics
  • Review the concept of energy conservation in quantum systems
  • Examine the transition probability calculations in quantum mechanics
  • Read Chapter XVII of Messiah's quantum mechanics textbook for deeper insights
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osturk
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Hi people,

Time-dependent perturbation theory allows for transitions to excited states, through a sinusoidal perturbation whose frequency is smaller than the energy difference between the states. (That is, P_{a \rightarrow b}=\frac{sin^{2}[(\omega_{0}-\omega)t/2]}{(\omega_{0}-\omega)^2}. Although the transition probability falls rapidly, as incident light frequency falls below the natural frequency, it's still non-zero..)

So in the "rare" event of absorption of a photon with insufficient energy, where does the lacking energy come from? Can you comment on the energy conservation in such an event?
 
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Messiah discusses this in Chap XVII, and there he points out that the nonconservation of energy is only apparent, since it is the unperturbed energy (the energy difference between the original states) which is not conserved, rather than the total energy of the system including the perturbation.
 
thanks for the answer. I only have the 1st volume of Messiah's book, and a google search on the issue returns nothing, so..

Bill_K said:
... nonconservation of energy is only apparent, since it is the unperturbed energy (the energy difference between the original states) which is not conserved, rather than the total energy of the system including the perturbation.

But, the total energy of the system seems to be increased already.. initially we have a photon with \hbar\omega, and then, a system with energy \hbar\omega_{0}, but no photon. surely energy should be conserved, but how is it compensated?
 

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