It depends on what you mean by "axe o rotation". If you mean the points that are left fixed by the rotation/translation, then, as Doc Al said, you can find this line by intersecting the planes orthogonal to the velocities of two points of the body. In general, not only it's not true that this line goes through the center of mass, but it can even lie outside the body.
For instance, the instantaneous axe of rotation of a wheel af a car is the point the wheel touches the ground, and the instantaneous axe for the moon is the center of the earth.
Moreover the IA of rotation depends on the reference frame you are in, so it has no real physical significance.
What has relevance is the direction of this axe, not it's origin. So, don't really bother on finding such axe: you can say that the body rotates about a direction, and you can put the origin of the axe wherever you like, the rotation doesn't change.