First law of thermodynamics applied to a closed system

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Homework Help Overview

The discussion revolves around applying the first law of thermodynamics to a closed system involving a well-insulated rigid steel tank containing water. The problem involves calculating specific volumes and total internal energy at two states of water, which transitions from a saturated liquid-vapor mixture to a fully vaporized state.

Discussion Character

  • Mixed

Approaches and Questions Raised

  • Participants discuss the calculations of specific volume and internal energy at different states of water, referencing thermodynamic tables for values. There are attempts to clarify the application of vapor quality in calculations, with some participants expressing confusion over the correct proportions of liquid and vapor in the mixture.

Discussion Status

Several participants have provided feedback on the original poster's calculations, noting errors and misunderstandings regarding the application of vapor quality and the properties of the mixture. There is ongoing exploration of the correct approach to calculating the properties of the liquid-vapor mixture, with some guidance offered about using the correct proportions for internal energy calculations.

Contextual Notes

Participants are working under the constraints of the problem statement, which specifies the conditions of the system and the states of water involved. There is a focus on ensuring that assumptions about the properties of the mixture are correctly applied, particularly regarding the definitions of quality and the implications of heating the water.

Luchekv
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Homework Statement


- A well insulated rigid steel tank contains water (only)
- A resistance heating element (240V, 3.67Amp) designed to heat the water as well as inlet and outlet valves for - the water.
- At state-1, the water is in a saturated liquid-vapor mixture state at P(abs)=100kPa, measures 5kg and the portion of it in liquid form is 75%, the rest being vapor
- To reach state-2, more power is supplied to the heater, but just enough to vaporize all the remaining liquid. When all the liquid is vaporized, the heater is switched off.

1.) Calculate the (average) specific volume (units: m3 /kg) for the water at state-1.
2.) Calculate the total internal energy (units: kJ) for the water at state-1.
3.) Calculate the (average) specific volume (units: m3 /kg) for the water at state-2.

Homework Equations


yavg=yf+x(yfg)
ΔU=mΔu

The Attempt at a Solution



1.) [/B]I went to the tables and read of the vf and vg data @ 100kPa. For quality, seeing as 75% is liquid that would make it 0.35. I applied that data to the following equation: yavg=yf+x(yfg) and got:
vavg = 0.001043+0.25(1.6941-0.001043) = 0.4243 m^3/kg

2.) I did the same thing for this part I read the data for uf and ufg from the tables @ 100kPa and applied it to this equation: yavg=yf+x(yfg) and got:
uavg=417+0.25(2088.2) =939.65
Which I then plugged into ΔU=mΔu, seeing as its the same state I only needed uavg:
U= 5kg*1147.87 = 4695.25 kJ

3.) In the statement it says at state 2 all the water is vaporized which would make it a quality of 1 and it would be a saturated vapor..so all I did was read of the value for saturated vapor at 100kPa which is 1.6941m^3/kg

Wasn't 100% on a few of these, any feed back would be great :)
Thank you in advance
 
Last edited:
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Luchekv said:

Homework Statement


- A well insulated rigid steel tank contains water (only)
- A resistance heating element (240V, 3.67Amp) designed to heat the water as well as inlet and outlet valves for - the water.
- At state-1, the water is in a saturated liquid-vapor mixture state at P(abs)=100kPa, measures 5kg and the portion of it in liquid form is 75%, the rest being vapor
- To reach state-2, more power is supplied to the heater, but just enough to vaporize all the remaining liquid. When all the liquid is vaporized, the heater is switched off.

1.) Calculate the (average) specific volume (units: m3 /kg) for the water at state-1.
2.) Calculate the total internal energy (units: kJ) for the water at state-1.
3.) Calculate the (average) specific volume (units: m3 /kg) for the water at state-2.

Homework Equations


yavg=yf+x(yfg)
ΔU=mΔu

The Attempt at a Solution



1.) [/B]I went to the tables and read of the vf and vg data @ 100kPa. For quality, seeing as 75% is liquid that would make it 0.35. I applied that data to the following equation: yavg=yf+x(yfg) and got:
vavg = 0.001043+0.35(1.6941-0.001043) = 0.5936 m^3/kg

If 75% is liquid and 35% is vapor, where did the extra 10% come from?
 
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*sigh* Stupid error... how embarrassing haha. Apart from that is the way I went about it correct?
 
Luchekv said:
*sigh* Stupid error... how embarrassing haha. Apart from that is the way I went about it correct?
You seemed to start off OK, but I stopped checking when I got to the quality mistake.
 
I have gone back and fixed the errors.
 
Part 3 is done incorrectly. The pressure is no longer 100 kPa after the water is heated to the point where all the liquid water has vaporized. But, what actually is still constant?

Chet
 
Luchekv said:

Homework Statement


- A well insulated rigid steel tank contains water (only)
- A resistance heating element (240V, 3.67Amp) designed to heat the water as well as inlet and outlet valves for - the water.
- At state-1, the water is in a saturated liquid-vapor mixture state at P(abs)=100kPa, measures 5kg and the portion of it in liquid form is 75%, the rest being vapor
- To reach state-2, more power is supplied to the heater, but just enough to vaporize all the remaining liquid. When all the liquid is vaporized, the heater is switched off.

1.) Calculate the (average) specific volume (units: m3 /kg) for the water at state-1.
2.) Calculate the total internal energy (units: kJ) for the water at state-1.
3.) Calculate the (average) specific volume (units: m3 /kg) for the water at state-2.

Homework Equations


yavg=yf+x(yfg)
ΔU=mΔu

The Attempt at a Solution



1.) [/B]I went to the tables and read of the vf and vg data @ 100kPa. For quality, seeing as 75% is liquid that would make it 0.35. I applied that data to the following equation: yavg=yf+x(yfg) and got:
vavg = 0.001043+0.25(1.6941-0.001043) = 0.4243 m^3/kg

No, you still aren't applying the concept of vapor quality correctly to calculate the properties of a mixture of vapor and liquid.

If x% is vapor, then (100 - x%) will be liquid, and you must calculate the thermo properties of the mixture accordingly.

https://www.engineersedge.com/thermodynamics/steam_tables.htm
 
SteamKing said:
No, you still aren't applying the concept of vapor quality correctly to calculate the properties of a mixture of vapor and liquid.

If x% is vapor, then (100 - x%) will be liquid, and you must calculate the thermo properties of the mixture accordingly.

https://www.engineersedge.com/thermodynamics/steam_tables.htm
Hmmm. It looks correct to me. 0.25x1.6941+0.75x0.001043
What am I missing?

Chet
 
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Chestermiller said:
Hmmm. It looks correct to me. 0.25x1.6941+0.75x0.001043
What am I missing?

Chet
Below is the OP's calculation, Chet. Notice something different w.r.t. your calculation?
Luchekv said:
vavg = 0.001043+0.25(1.6941-0.001043) = 0.4243 m^3/kg
 
  • #10
I looked on the website you supplied and read this "v=vf+x(vfg)" isn't that what I've done? The way I look at it is..if 75% is liquid its closer to the Sat Liq point (0 quality) on the Tv diagram.

Also, me and Chet get the same answer?
Chestermiller said:
Part 3 is done incorrectly. The pressure is no longer 100 kPa after the water is heated to the point where all the liquid water has vaporized. But, what actually is still constant?

Chet

The mass would be constant so then I could use v = V/m ...but I don't have volume so I would then need to rearrange ρ=m/V but I don't have ρ...would it be correct to assume temperature is constant as well? since its only moving along (horizontally) the Tv diagram...because if that's the case I can use the temperature @ 100kPa in the tables to get the density for water for that temperature
 
  • #11
SteamKing said:
Below is the OP's calculation, Chet. Notice something different w.r.t. your calculation?
It's not really different. It's just doing the factoring differently. The result is the same.

Chet
 
  • #12
Chestermiller said:
It's not really different. It's just doing the factoring differently. The result is the same.

Chet
You and the OP are missing the point.

Take a look at the OP's calculation of internal energy:
Luchekv said:
uavg=417+0.25(2088.2) =939.65

The OP is taking 100% of the internal energy of the liquid phase ...
 
  • #13
I'm really confused now haha... I know x = mVapor/mTotal...if 25% is vapor of the 5kg of mass = 1.25kg/5kg = 0.25?

Thank you for your patience guys
 
  • #14
Luchekv said:
I'm really confused now haha... I know x = mVapor/mTotal...if 25% is vapor of the 5kg of mass = 1.25kg/5kg = 0.25?

Thank you for your patience guys
Yes, 25% of the mass is vapor, and 75% of the mass is liquid. When you figure the thermo properties for a liquid-vapor mixture, you've got to use the proportions of each property to find the property for that combination of liquid and vapor.

For example, if you want to calculate the internal energy of this mixture of liquid water and water vapor, you can't use 100% of the internal energy of the liquid and 25% of the internal energy of the vapor, you can only have 75% of the internal energy of the liquid, because only 75% of the sample is liquid ...

That's why I linked to this article:

https://www.engineersedge.com/thermodynamics/steam_tables.htm
 
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  • #15
SteamKing said:
You and the OP are missing the point.

Take a look at the OP's calculation of internal energy:The OP is taking 100% of the internal energy of the liquid phase ...
Oh. I assumed the 2088 was the difference between the liquid and the vapor.

Chet
 
  • #16
I understand what you're saying, but if I'm to follow this equation "v=vf+x(vfg)" and just above I worked the quality out to be 0.25..I don't see what else I'm supposed to use for x ?

2088 is the difference "ufg" (2505.6-417)
 
  • #17
Luchekv said:
I looked on the website you supplied and read this "v=vf+x(vfg)" isn't that what I've done? The way I look at it is..if 75% is liquid its closer to the Sat Liq point (0 quality) on the Tv diagram.

Also, me and Chet get the same answer?

The mass would be constant so then I could use v = V/m ...but I don't have volume so I would then need to rearrange ρ=m/V but I don't have ρ...would it be correct to assume temperature is constant as well? since its only moving along (horizontally) the Tv diagram...because if that's the case I can use the temperature @ 100kPa in the tables to get the density for water for that temperature
Both the mass of water and the volume of the container are constant. So, if that's the situation, how does the average specific volume in case 1 compare with the specific volume of the pure vapor in case 3?

Chet
 
  • #18
Ok..so I have 5kg of water and my spec volume for state 1 is 0.4243m^3/kg...to get the volume of state one that would be m*v1 = 2.1215m^3/kg

considering volume is constant V1=V2...therefore v2=V2/m ---> v2=2.1215/5= 0.4243...which should be the case since no mass has left the system and the volume hasn't changed.

I'm still confused as to what's wrong with my quality equations...is my quality value wrong? or the numbers I've used from the tables? I've used the equation provided. I don't see what is incorrect. How am I using 100% of the liquid phase for u when I've followed the equation uavg=uf +xufg ? :\ was I supposed to multiply 0.75 to uf? if so..then that's not really following the equation.
 
Last edited:
  • #19
OK. So the specific volume of the vapor for case 3 is 0.4243 m^3/kg. From your steam tables, what saturation pressure, temperature, and specific internal energy of the vapor does this correspond to? For 5 kg of this vapor, what is its internal energy?

Chet
 
  • #20
Apologies for the delay, had a mid semester exam to study for,
(Had to interpolate)
Sat Pressure: 439.229kPa (0.46242-0.41392)/(0.4243-0.41392)=(400-450)/(x-450)
Temp: 146.982 degrees Celsius (0.46242-0.41392)/(0.4243-0.41392)=(143.61-147.9)/(x-147.9)
Internal energy (avg): 2556.24 kJ/kg (0.46242-0.41392)/(0.4243-0.41392)=(2553.1-2557.1)/(x-2557.1)

U = m* uavg = 12781.2 kJ
 
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  • #21
I assume by the like, that it is correct haha?
 
  • #22
Luchekv said:
I assume by the like, that it is correct haha?
Yes. I didn't check your arithmetic, but your approach is correct.

Chet
 
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  • #23
Awesome, thank you! - I will double check the interpolation regardless
 

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