Free energy question involving Kp and deltaG

AI Thread Summary
The discussion revolves around calculating the Gibbs reaction energy and equilibrium constant (Kp) for the reaction involving ammonia and nitric oxide. The user successfully calculated the Gibbs reaction energy as -1815 kJ but is uncertain about using this value in the equation ln(Kp) = -ΔG0/(RT). It is clarified that the ΔG0 from part A should be used in the equation, not the individual ΔG values for the reactants or products. Additionally, the user is reminded to ensure they have the standard heats of formation to calculate the reaction enthalpy. Accurate calculations and understanding of the equations are crucial for solving these thermodynamic problems.
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Homework Statement



The following reaction takes place at standard conditions

4NH3(g)+6NO(g)----->5N2(g)+6H20

A)calculate reaction enthalpy and Gibbs reaction energy

B)Calculate Kp


Homework Equations



the table gives the following values for deltaG0f[X]
NH3(g)=-16.5 Kj/mol
NO(g)=87.6 KJ/mol
H20(g)=-228.6 KJ/mol

ln(Kp)=-deltaG/(RT)


The Attempt at a Solution



I finished part a) and found gibbs reaction energy to be -1815 KJ

For part b) i am unsure of what to enter for deltaG in the equation ln(Kp)=-deltaG/(RT). Do I use the reaction energy calculated from part a), deltaG for NH3, NO, or H20? Any help is appreciated, thanks!
 
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you would use the standard DG found by this formula:
∑nΔGoproducts - ΣmΔGoreactants
 
-the n and m being the coefficients for each molecule
 
hahaha158 said:

Homework Statement



The following reaction takes place at standard conditions

4NH3(g)+6NO(g)----->5N2(g)+6H20

A)calculate reaction enthalpy and Gibbs reaction energy

B)Calculate Kp

Homework Equations



the table gives the following values for deltaG0f[X]
NH3(g)=-16.5 Kj/mol
NO(g)=87.6 KJ/mol
H20(g)=-228.6 KJ/mol

ln(Kp)=-deltaG/(RT)

The Attempt at a Solution



I finished part a) and found gibbs reaction energy to be -1815 KJ

For part b) i am unsure of what to enter for deltaG in the equation ln(Kp)=-deltaG/(RT). Do I use the reaction energy calculated from part a), deltaG for NH3, NO, or H20? Any help is appreciated, thanks!
You use the ΔG0 that you calculated in part a (I didn't check your arithmetic). (Also, that should not be a ΔG in the equation; it should be ΔG0). To get the standard reaction enthalpy, you need to know the standard heats of formation. Did they give you these?

Chet
 
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