Gibb's phase rule and counting phases

AI Thread Summary
In the discussion on Gibb's phase rule, a user questions the calculation of degrees of freedom for a mixture of four immiscible liquids. The confusion arises over the number of phases, with the user initially believing there is only one liquid phase. However, it is clarified that each immiscible liquid counts as a separate phase, leading to four distinct liquid phases. Applying Gibb's phase rule, the degrees of freedom are calculated as F = C - P + 2, resulting in F = 4 - 4 + 2 = 2. This highlights the importance of accurately identifying phases in phase rule calculations.
member 392791
Hello,

I was wondering, suppose I had a mixture of a few liquids that were immiscible, say 4.

Now, when calculating the degrees of freedom, I am confused about the number of phases.

I think the number of components is 4, but the number of phases should be 1, liquid, right? Or does each component in the liquid phase count as one phase. I have seen problems that seem contradictory to what I think the answer should be

F = C - P + 2

F = 4 - 1 + 2 = 5
 
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Four mutually immiscible liquids? Four liquid phases.
 
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