The discussion focuses on understanding unit cancellation in the equation involving Planck's constant and photon energy. The correct unit for frequency is s-1, not s, indicating a likely typo in the provided equation. The cancellation of units occurs when the second from Planck's constant (J·s) interacts with the inverse second from frequency (s-1), resulting in energy measured in joules. Participants clarify that only quantities with the same units can be added or subtracted, confirming that the kinetic energy of the photoelectron is also expressed in joules. The equation illustrates the relationship between a photon's energy and its frequency, emphasizing the importance of accurate unit representation.