How Do I Calculate the Volume of Air Needed for Complete Combustion of Gasoline?

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To calculate the volume of air needed for the complete combustion of one liter of gasoline, the balanced reaction shows that 6.15 moles of octane require 76.875 moles of O2. Using the ideal gas law, the volume of oxygen needed is calculated to be 9,163.5 liters. However, since air contains 20.5% oxygen, the total volume of air required is approximately 45,817.5 liters. A clarification indicates that the initial calculation should use the total atmospheric pressure rather than just the partial pressure of oxygen. The final consensus confirms the correct volume of air needed for combustion.
Gil-H
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Homework Statement


What volume of air (T=25C, P=1atm) is required
for complete combustion of one litter of gasoline?
The partial pressure of oxygen in the air is 0.205 atm.
One litter of gasoline contains 6.15 moles octane C8H18.


Homework Equations


The unbalanced reaction is:
C8H18 + O2 --> CO2 + H2O
The ideal gas law:
PV = nRT


The Attempt at a Solution


The balanced reaction is:
C8H18 + (25/2)O2 --> 8CO2 + 9H2O
So 6.15 moles octane requires 6.15*12.5 = 76.875 moles O2.
With the ideal gas law I get:
PV = nRT
(0.205)V=(76.875)(0.082)(298)
V = 9,163.5 L

Is this the correct answer?
My friend beleives it is,
but I think that this value is just the volume of oxygen needed,
and the volume of air needed is V = (9,163.5/0.2) = 45,817.5 L
 
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Your friend is right.

Your approach would be correct if you would use not partial pressure of the oxygen, but 1 atm.

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