How Do Particles Leak from a Container and Reach a Spherical Cap?

J_M_R
Messages
20
Reaction score
0

Homework Statement



An ideal gas satisfying the Maxwell-Boltzmann distribution is leaking from a container of the volume V through a circular hole of area A'. The gas is kept in the container under pressure P and temperature T. The initial number density (concentration) is given by n0=N/V.

Find the number of particles leaking from the container per unit of time and reaching a spherical cap with the radius R and the height h, h<R. The centre of the sphere is positioned exactly at the centre of the hole and the base of the cap is in the plane parallel to one of the container's wall.

Homework Equations



Maxwell-Boltzmann Distribution: f(vi) = √(m/(2πkT))*(e^[(mvi^2)/(2kT)])

where vi stands for either vx, vy, or vz.

k - Boltzmann constant.

The Attempt at a Solution


[/B]
When looking at the hole of the box, if the hole has length vxdt, then the portion of particles with velocity vx getting out of the hole (of area A') in time dt is: n0A'vxdt = dN(vx).
Because the volume covered by particles in a moment of time, dt = A'vxdt. Where no=N/V

I have completed the work with a disk instead of a spherical cap at a distance from the box, removing the y and z velocity components and replacing them with polar coordinates for velocity and think that to solve this problem spherical coordinates are required to replace the x, y and z velocity components associated with the cap.

I have got to this point below but do not know how to derive the limits of the triple integral:

N = no * A' * dt * (m/(2*pi*k*T))^(3/2) ∫ (v * d^3v * e^-(m*v^2/(2*k*T)))

The upper limit of integration is v2 and the lower limit is v1 which are 3-dimensional velocities.

where v^2 = vx^2 + vy^2 + vz^2

and d^3v = dvx dvy dvz = v^2 sinӨdӨdφ

I understand that I need to use a triple integral but I am unsure how to obtain the limits using spherical coordinates, if anybody is able to give me some hints that would be much appreciated.
 
Last edited:
Physics news on Phys.org
There is a dv missing in the last equation.

If you plug in your expression for d3 into the integral, you get two integrals that are easy to solve and one where you have to integrate a function of the type of ##v^3 e^{-v^2}##, which can be integrated with standard methods.
 
Thread 'Need help understanding this figure on energy levels'
This figure is from "Introduction to Quantum Mechanics" by Griffiths (3rd edition). It is available to download. It is from page 142. I am hoping the usual people on this site will give me a hand understanding what is going on in the figure. After the equation (4.50) it says "It is customary to introduce the principal quantum number, ##n##, which simply orders the allowed energies, starting with 1 for the ground state. (see the figure)" I still don't understand the figure :( Here is...
Thread 'Understanding how to "tack on" the time wiggle factor'
The last problem I posted on QM made it into advanced homework help, that is why I am putting it here. I am sorry for any hassle imposed on the moderators by myself. Part (a) is quite easy. We get $$\sigma_1 = 2\lambda, \mathbf{v}_1 = \begin{pmatrix} 0 \\ 0 \\ 1 \end{pmatrix} \sigma_2 = \lambda, \mathbf{v}_2 = \begin{pmatrix} 1/\sqrt{2} \\ 1/\sqrt{2} \\ 0 \end{pmatrix} \sigma_3 = -\lambda, \mathbf{v}_3 = \begin{pmatrix} 1/\sqrt{2} \\ -1/\sqrt{2} \\ 0 \end{pmatrix} $$ There are two ways...
Back
Top