I believe changing the order of the terms is going to have an effect on the sum at least. Suppose (x_{1},x_{2},...,x_{n}) = (1, 2, ..., n) and (y_{1},y_{2},...,y_{n}) = (n, ..., 1). In general, \sum_{j\displaystyle{=}1}^n jx_{j} is not equal to \sum_{j\displaystyle{=}1}^n jy_{j}.
Here's a possible approach to the question:
Let A be the set of permutations (x_{1},x_{2},...,x_{n}) satisfying \sum_{j\displaystyle{=}1}^n jx_{j} \leq a and B be the set of permutations (y_{1},y_{2},...,y_{n}) satisfying \sum_{j\displaystyle{=}1}^n jy_{j} \geq \frac{n(n+1)^2}{2}-a. Let |A| and |B| denote the number of elements in A and B respectively. Our goal is to show that |A| = |B| (refer to the second post). We will prove this statement in 2 parts.
Part 1: |A| \leq |B|
We prove this by showing that for every permutation (x_{1},x_{2},...,x_{n}) in A, we can change the order of the terms in a certain way to create a permutation (y_{1},y_{2},...,y_{n}) that will be in B. This will mean that |B| cannot be smaller than |A|, and thus |A| \leq |B| (since this mapping from set A to set B is injective or one-to-one). Now, consider a permutation (x_{1},x_{2},...,x_{n}) in A. We will try to shuffle the terms around in a certain manner, and show that the new permutation (y_{1},y_{2},...,y_{n}) we get is an element of B. What is one obvious guess for (y_{1},y_{2},...,y_{n})? Try then to show that \sum_{j\displaystyle{=}1}^n jy_{j} \geq \frac{n(n+1)^2}{2}-a, given the fact that \sum_{j\displaystyle{=}1}^n jx_{j} \leq a.
Part 2: |B| \leq |A|
The idea of this part is the same as before; we show that for every permutation (y_{1},y_{2},...,y_{n}) in B, we can change the order of the terms in a certain way to create a permutation (x_{1},x_{2},...,x_{n}) that will be in A. The structure of the proof is similar to Part 1.
Combining our results for both parts, we get |A| = |B| and we are done.