How Does Reversible Expansion Calculate Work in Thermodynamics?

AI Thread Summary
The discussion revolves around a thermodynamics problem involving a reversible expansion of a gas. The participant struggles to reconcile their calculated work, which is -75.0 L atm or -7.60x10^3 J, with the professor's answer of -22.8 J. They correctly identify the change in volume as 15.0 L and apply the pressure of 5.00 atm to calculate work, but are unclear on how the professor arrived at a significantly different value. The participant seeks confirmation that their calculations are accurate and expresses confusion over the discrepancy. The conversation highlights the complexities of thermodynamic calculations and the importance of understanding the underlying principles.
Puchinita5
Messages
178
Reaction score
0

Homework Statement



Okay i feel like I'm going crazy. Here is a sample problem my professor gave me. But I cannot figure out for my life how he got his answer and it hsould be very simple.


A 10.0 mol sample of a perfect gas having Cv = 2.0R undergoes a reversible expanion form 5.00 L to 20.0 L at 5.00 atm of pressure. Calculate q, w, delta U, and delta H for this process..

Solving for work, he has...


w = -PdV = -5(20-5) = -22.5 L atm = -22.8 J

HOW ON EARTH does he get those numbers?







Homework Equations





The Attempt at a Solution

 
Physics news on Phys.org
dV is the change in volume, which is (20.0-5.00 L)=15.0 L
-P is the given pressure x(-1), -P = -5.00 atm
w = -PdV= -5.00*15.0 L atm = -75.0 L atm
Since L atm is a unit of work, it can be converted to J:
1 L atm = 101.325 J, so -75.0(101.325) J = -7.60x10^3 J = w

I'm not sure what else your professor did to get to his answer, but this is what I got based on what was given.
 
dV is the change in volume, which is (20.0-5.00 L)=15.0 L
-P is the given pressure x(-1), -P = -5.00 atm
w = -PdV= -5.00*15.0 L atm = -75.0 L atm
Since L atm is a unit of work, it can be converted to J:
1 L atm = 101.325 J, so -75.0(101.325) J = -7.60x10^3 J = w

I'm not sure what else your professor did to get to his answer, but this is what I got based on what was given.
 
thank you! I just needed confirmation that I wasn't missing something. That was exactly what I thought the answer should be
 
Thread 'Confusion regarding a chemical kinetics problem'
TL;DR Summary: cannot find out error in solution proposed. [![question with rate laws][1]][1] Now the rate law for the reaction (i.e reaction rate) can be written as: $$ R= k[N_2O_5] $$ my main question is, WHAT is this reaction equal to? what I mean here is, whether $$k[N_2O_5]= -d[N_2O_5]/dt$$ or is it $$k[N_2O_5]= -1/2 \frac{d}{dt} [N_2O_5] $$ ? The latter seems to be more apt, as the reaction rate must be -1/2 (disappearance rate of N2O5), which adheres to the stoichiometry of the...
Back
Top