How to calculate heat of reaction of a single replacement reaction?

  • Thread starter Thread starter member 508213
  • Start date Start date
  • Tags Tags
    Heat Reaction
AI Thread Summary
To calculate the heat of reaction (ΔHrxn) for single replacement reactions, it's essential to gather specific details about the reaction, including the reagents, their phases, and any catalysts involved. The common equations for determining ΔHrxn include ΔH°=∑ΔvpΔH°f(products)−∑ΔvrΔH°f(reactants) and ΔH=q=mcΔT. In the context of mixing CuSO4 and iron in water, the calorimetry equation ΔE=mCΔT can be applied to measure the temperature change. To find the overall heat of the reaction experimentally, one must record the temperature change and then calculate ΔE. To convert ΔE to ΔH, it is necessary to divide by the number of moles of the limiting reactant, which provides the molar heat of the reaction. This approach ensures accurate results for the heat of reaction in a lab setting.
member 508213
In lab I am doing a series of single replacement reactions and I am curious how to calculate the heat of reaction for single replacement reactions and what measurements to take so I can calculate it?
 
Chemistry news on Phys.org
Since you're doing a lab I would assume that you were already taught the relevant equations and procedures...

Anyways, I think you should provide more details about the reaction.

What are the reagents? What are the phases of the reactants? Catalysts?

Details like these are important in order to determine the ΔHrxn.

As a refresher, the most common equations used to find the ΔHrxn are
  • ΔH°=∑ΔvpΔH°f(products)−∑ΔvrΔH°f(reactants)
  • ΔH=q=mcΔT
 
  • Like
Likes 1 person
I plan on mixing CuSO4 and Iron in water and I know that for calorimetry you use deltaE=mCdeltaT but I am unsure of how this would work with a single replacement reaction in water? What would be necessary to be able to obtain the overall heat of the reaction BY LAB not theoretical
 
To make more clear what I am trying to ask (sorry for not asking clearly) is:
Would it give me the correct heat of reaction if I put Iron and CuSO4 in water...recorded the change in temperature and used DE=mCDT?

But once I find DeltaE don't I have to do something else to find DeltaH like divide by the number of moles of reactant or something like that I forget? This is where my confusion is greatest..
 
Austin said:
But once I find DeltaE don't I have to do something else to find DeltaH like divide by the number of moles of reactant

Depends on what you aim at. If at the molar heat of the reaction (which is the most logical thing), then yes.
 
It seems like a simple enough question: what is the solubility of epsom salt in water at 20°C? A graph or table showing how it varies with temperature would be a bonus. But upon searching the internet I have been unable to determine this with confidence. Wikipedia gives the value of 113g/100ml. But other sources disagree and I can't find a definitive source for the information. I even asked chatgpt but it couldn't be sure either. I thought, naively, that this would be easy to look up without...
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert? What is so special with a full p orbital? Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive. Can someone explain it to me? Thanks!!
Back
Top