How to identify stainless steel?

In summary, stainless steel does not attract magnets and has a distinctive appearance, but some types are magnetic. One way to test for stainless steel is by using acid and a chelating agent to separate chromium from iron. Other methods include using alkali and oxidants to separate the two elements, with the resulting solutions and precipitates having distinct colors.
  • #1
kenny1999
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I know that stainless steel does not attract magnet, I know that stainless steel has appearance that looks like stainless steel, but sometimes it is quite difficult to tell. In addition to magnet test, any further test I can do in my home?
 
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  • #2
kenny1999 said:
I know that stainless steel does not attract magnet,
Then you "know" incorrectly. Some stainless steel IS magnetic. Google it.
 
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  • #3
Like phinds said, stainless steel like martensitic steel are magnetic.

Stainless steel contains fair amount of Cr. Cr is the main reason why stainless steels are "stainless".

I never tried this, but I think this is relatively safe (make sure you wear gloves, goggles, and lab coat; do not get the chemicals on your skin) so I'll try my best to answer the OP's question.
You could try partially dissolving stainless steel in acid (for example HCl 1 - 2M), take the water solution, and use some sort of chelating agent. Then you could try using NaOH (1 - 2 M?) to change the pH so that Fe(chelate) precipitates, leaving Cr in the water solution. Check the color and see if it is the supposed to be color of Cr(chelate). I believe this method can be quantitative as well.

I don't know what chelates should be used, so you need to look that up. HCl and NaOH can be bought by general consumers in my country.
 
  • #4
HAYAO said:
Stainless steel contains fair amount of Cr. Cr is the main reason why stainless steels are "stainless".

I never tried this, but I think this is relatively safe (make sure you wear gloves, goggles, and lab coat; do not get the chemicals on your skin) so I'll try my best to answer the OP's question.
You could try partially dissolving stainless steel in acid (for example HCl 1 - 2M), take the water solution, and use some sort of chelating agent. Then you could try using NaOH (1 - 2 M?) to change the pH so that Fe(chelate) precipitates, leaving Cr in the water solution. Check the color and see if it is the supposed to be color of Cr(chelate). I believe this method can be quantitative as well.

I don't know what chelates should be used, so you need to look that up. HCl and NaOH can be bought by general consumers in my country.
Do you need chelates?
Qualitative separation of Cr and Fe has other possibilities.
Like ´hydrogen peroxide in basic solution. Fe is oxidized to brown Fe(OH)3 precipitate (you need stronger oxidants for ferrate), while Cr is oxidized to yellow chromate solution.
 
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  • #5
snorkack said:
Do you need chelates?
Qualitative separation of Cr and Fe has other possibilities.
Like ´hydrogen peroxide in basic solution. Fe is oxidized to brown Fe(OH)3 precipitate (you need stronger oxidants for ferrate), while Cr is oxidized to yellow chromate solution.
Oh yeah, didn't think about that. Haha. Thanks. :-p
 
  • #6
Even without any chelation, adding alkali to Fe solution precipitates either Fe(OH)2, which is at first white but then rapidly turns green and then brown of Fe(OH)3 due to air oxygen, or directly the brown Fe(OH)3. Neither Fe(OH)2 nor Fe(OH)3 will dissolve in excess alkali, unless you apply a strong oxidant like hypochlorite, and then the solution is purple.
Cr(OH)3 precipitate is grayish green and unlike Fe(OH)3 it dissolves in alkali without adding oxidant, giving a solution that is green. Oxidizing Cr(OH)3 in alkali can be done not only by hypochlorite but also by hydrogen peroxide, and the colour turns to yellow.
Solutions and precipitates of iron:
https://woelen.homescience.net/science/chem/solutions/fe.html
Solutions and precipitates of chromium:
https://woelen.homescience.net/science/chem/solutions/cr.html
 

1. What is the best method for identifying stainless steel?

The most reliable method for identifying stainless steel is through spark testing. This involves using a grinder or file to create sparks on the surface of the steel. The color, length, and shape of the sparks can help determine the type of stainless steel.

2. Can stainless steel be identified by its magnetism?

Yes, magnetism can be a useful indicator of stainless steel. Most stainless steels are non-magnetic, but some may have a slight magnetic response due to the presence of other elements. However, this method is not always accurate, and other tests should be performed for confirmation.

3. How can I tell the difference between 304 and 316 stainless steel?

304 and 316 stainless steel are two of the most commonly used grades of stainless steel. They have similar appearances, but 316 stainless steel contains more nickel and molybdenum, making it more resistant to corrosion. To differentiate between the two, a chemical test can be performed using a solution of copper sulfate and sulfuric acid. 316 stainless steel will turn a brownish color, while 304 stainless steel will not react.

4. Is there a way to identify stainless steel without damaging the surface?

Yes, there are non-destructive methods for identifying stainless steel. These include using a handheld X-ray fluorescence (XRF) analyzer or a spectrometer. These tools can determine the chemical composition of the steel without causing any damage to the surface.

5. Can I use a magnet to identify different types of stainless steel?

While magnetism can be a helpful indicator, it is not always reliable for identifying different types of stainless steel. Some stainless steels are non-magnetic, while others may have varying levels of magnetism. It is best to use multiple methods for accurate identification.

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