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[EDIT: I retyped the LaTeX, which somehow got distorted. I hope it's not a bug in the forums software?]rude man said:What you are still not recognizing is that Em≠0Em≠0. It is in fact the field that accounts for the battery emf.
The battery emf is a thermodynamic quantity the electrochemical potential.
Your idea of this artificial split of the electric field is highly unphysical and misleading.
At best what seems to be something related to this split is to use the Coulomb-gauged electromagnetic potentials, i.e., you use the homogeneous Maxwell equations to introduce the potentials (in Heaviside-Lorentz units)
$$\vec{E}=-\frac{1}{c} \partial_t \vec{A} - \vec{\nabla} \Phi, \quad \vec{B}=\vec{\nabla} \times \vec{A}$$
The Coulomb gauge-fixing condition is
$$\vec{\nabla} \cdot \vec{E}=-0.$$
Then you have
$$\vec{\nabla} \cdot \vec{E}=-\Delta \Phi=\rho$$
and thus a split of ##\vec{E}## in a solenoidal field ##-(1/c) \partial_t \vec{A}## and a conservative source field ##-\vec{\nabla} \Phi##. But as this analysis clearly shows both parts are gauge dependent and thus unobservable mathematical auxilliary fields. You cannot easily interpret these parts physically in any way. Only the one and only electric field components ##\vec{E}## are physical.
In chemical equilibrium (i.e., for the open battery in the static state) you have a double layer of ions around the electrodes within which there is a static electric field, which is static and thus a pure source field with ##\vec{\nabla} \times \vec{E}=0##.
For the closed battery you have a current running through the circuit (including the battery). In the stationary state, where the current is constant, again ##\vec{\nabla} \times \vec{E}##. Then you get ##\mathcal{E}=U-R I=0##, where is the EMF of the battery (in this stationary non-equilibrium state with a current running through).
For a detailed discussion, see a physical-chemistry book like Morimer or Atkins.
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