Ideal gas volume work expression (adiabatic)

AI Thread Summary
The discussion focuses on solving a problem related to the ideal gas volume work expression during an adiabatic process. It emphasizes applying the first law of thermodynamics, noting that in an adiabatic process, heat exchange (Q) is zero, leading to the relationship dU = -dW. The internal energy change is expressed as dU = nC_vdT, while work is defined as dW = -PdV, allowing for the derivation of the relationship between temperature and volume. The discussion also highlights the connection between specific heats, with the ratio γ = C_p/C_v, and culminates in the integration of the derived equations to establish a constant relationship between temperature and volume during the process. The thread concludes with encouragement to further explore the problem independently.
krootox217
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Homework Statement


I have the following task:
RMZh75X.png


Homework Equations

The Attempt at a Solution


But I don't understand how to solve it. Can somebody help me?[/B]
 
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1) I'd guess they want you to apply the first law of thermodynamics, but I'm not sure.
2) Here you just have to do what the statement says (with a substitution considering ideal gas).
3) Based on the result in 2) you are able to proof that.

You need the ideal gas equation and the connectedness between R, cp and cv
 
First one: The differential form of the 1º law of thermodynamics is:
dU = dQ-dW
Because it's an adiabatic process, there is no heat exchange, so Q = 0.
dU = -dW
Internal energy is a function of state that depends solely on the quantity of gas - a number n of moles - and the absolute temperature. That can be written as:
dU = nC_vdT
As for work:
dW = Fdx = PAdx = PdV
Where F is force and Adx is the infinitesimal change in volume.
You can now easily see that:
nC_vdT = -PdV
Second: First, remember that:
C_p = C_v + R
For convenience, let's adopt that:
C_p/C_v = \gamma
Using the famous equation, PV=nRT in the expression we derived in the first question:
nC_vdT = \frac{-nRT}{V}dV
\frac{dT}{T}+\frac{R}{C_v}\frac{dV}{V} = 0
And:
\frac{dT}{T}+(\gamma-1)\frac{dV}{V} = 0
Integrating:
\int \frac{dT}{T} dT + (\gamma-1)\int \frac{dV}{V} = 0
Which results in:
\ln (TV)^{(\gamma-1)} = cte
And finally:
(TV)^{(\gamma-1)} = cte
For a initial state (T_1, V_1) and a final state (T_2,V_2):
\frac{V_1}{V_2}^{(\gamma-1)} = \frac{T_2}{T_1}
Third: Try to solve the last one for yourself. Now it's easy ;)
 
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Thanks for the answers, I try to understand it and if I don't get everything, I ask again if that's ok :)
 
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