When a battery cell discharges, the internal resistance typically increases, leading to a constant drop in potential difference across the cell. Various models exist to represent battery behavior, with some employing a constant or variable electromotive force (EMF) alongside a variable internal resistance. Different battery chemistries require distinct modeling approaches, as no single model universally applies to all types. The EMF is defined as the potential difference between the terminals when they are externally connected. Understanding these dynamics is crucial for accurately assessing battery performance.