Christophe.V said:
Would it be possible (but probably less efficient) to make a cascade of subsequent voltage differentials, + to - to + to -, each one shielded from the previous by a zero potential wall with a small hole through which the electrons will pass? This wall would prevent the electrons from "seeing" the positive voltage and being slowed down again by it. In that manner no switching voltages are needed and the same voltage drop can be applied again and again.
Not as far as I can see. If you want the electron to go from a high potential to a low potential, then from high to low and repeat, you have to keep taking the electron from a low potential and putting it in a high potential. This takes energy. So on average, you'd be getting no acceleration at all.
I was in my lectures yesterday and the professor started off on a bit of a tangent about particle accelerators and how they function. It made me think immediately of this thread. He mentioned something which seemed very clever and possibly possible for you to achieve. Basically, you set up an electric field as you suggest, + - + - + - + -, etc, then you start to move the field slowly. The electrons will want to sit in the + sections of the electric field, so as you start to move the field, so the electrons move as well. In this way, the electrons are almost surfing the wave of this changing field.
The first particle accelerators though, according to him, were created simply using one big + to - potential. And of course the particles had to be placed in a vacuum to stop them from interacting with particles in the air.
Then you'll need some sort of way of detecting what's going on, so that you know that something's happening (or not).
Edit: After thinking about this electron surfing a little more, it's become apparent to me that this is exactly what was going on in the first instance I recommended to you. Basically, to set up this accelerating electric field, you will need to oscillate the electric field in the same switching on and off of electrodes that I was talking about before.
Also, to elaborate, this changing electric field is the only way (that I can see) that you can accelerate particles without just having one continuous potential drop.
Additionally, particles are focused using quite clever quadrupole magnets or some other arrangement of magnets.
Edit 2: I found a nice diagram explaining this surfing electrons:
http://particleadventure.org/accel_particles.html