Is the Maxwell Speed Distribution Applicable in an Ideal Gas with Fixed Energy?

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SUMMARY

The discussion centers on the applicability of the Maxwell speed distribution in an ideal gas system with fixed energy. It establishes that for an ideal gas of n particles constrained to a unit box, the phase space is defined as ([0,1]^3 x R^3)^n. The inquiry specifically addresses whether the velocity distribution of the first particle approaches the Maxwell speed distribution as n approaches infinity, under the condition of a constant energy surface E=n/2. The conclusion drawn is that the Maxwell speed distribution can indeed be derived from a uniform probability distribution over all systems with the same energy E.

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I want to know if the Maxwell speed distribution is the following.

An ideal gas system of n particles, say constrained to the unit box, has the phase space ([0,1]^3 x R^3)^n. That is, [0,1]^3 for the position of a particle, R^3 for the velocity, and all to the n since there are n particles. Now in this space we can take the surface of constant energy say E=n/2, so that the average energy of a single particle is 1. This surface has finite surface area, so we can put a uniform probability distribution on it, and ask what the distribution of the first particle's velocity is.

Is said distribution the Maxwell speed distribution, in the limit as n->infinity?

In other words, is the Maxwell speed distribution just the distribution for the velocity of a particle found in a system chosen uniformly over all systems of the same energy E?

Thanks in advance!
 
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The usual derivation assumes that the particles are in contact with some external reservoir and that the total energy can vary a bit. In the limit of infinite particles, I would expect that an exact energy gives the correct result, too.
 

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