Solving CycloHexane Isomerism: Find Total # Possible Isomers

AI Thread Summary
The discussion revolves around determining the total number of isomers for the molecular formula C6H12 that includes a cyclobutane ring. Initially, the calculation suggested there are 8 isomers, considering optical and geometrical isomerism in various compounds. However, upon further examination, particularly of Compound 3, it was clarified that it should yield only 3 isomers instead of 4 due to the symmetry of the cis form, which does not allow for optical isomerism. This adjustment leads to a revised total of 7 isomers, aligning with the book's assertion. The conversation highlights the importance of accurately assessing isomer types in organic chemistry.
phoenixXL
Messages
49
Reaction score
4
Question
Find out the total number of possible isomers with molecular formula C6H12 that contain a cyclobutane ring.

Attempted Solution
Untitled.png

In Compound 3, Optical Isomerism is possible (geometrical isomerism is also possible but is neglected due to presence of optical isomerism) about both the branches, hence it will be counted as 4 isomers

In Compound 4, Geometrical Isomerism is possible about the two branches, therefore it will be counted as 2 isomers

Counting All
: 1 + 1 + 4 + 2 = 8

Hence there are 8 isomers possible

Problem
The book where I found this question says that it consists only of 7 isomers.

Please help me out. Thanks for your time.
 
Chemistry news on Phys.org
Check 3rd.
 
Yes, I was suspecting the argument with compound 3.

Please Verify
Compound 3 will have cis & trans forms. The cis form due to symmetry would not have optical isomers whereas the trans form would have optical isomers. As a result there would be three isomers (rather than 4).
 
Yes, 3 not 4.
 
thank you for your time :)
 
Thread 'How to make Sodium Chlorate by Electrolysis of salt water?'
I have a power supply for electrolysis of salt water brine, variable 3v to 6v up to 30 amps. Cathode is stainless steel, anode is carbon rods. Carbon rod surface area 42" sq. the Stainless steel cathode should be 21" sq. Salt is pure 100% salt dissolved into distilled water. I have been making saturated salt wrong. Today I learn saturated salt is, dissolve pure salt into 150°f water cool to 100°f pour into the 2 gallon brine tank. I find conflicting information about brine tank...
Engineers slash iridium use in electrolyzer catalyst by 80%, boosting path to affordable green hydrogen https://news.rice.edu/news/2025/engineers-slash-iridium-use-electrolyzer-catalyst-80-boosting-path-affordable-green Ruthenium is also fairly expensive (a year ago it was about $490/ troy oz, but has nearly doubled in price over the past year, now about $910/ troy oz). I tracks prices of Pt, Pd, Ru, Ir and Ru. Of the 5 metals, rhodium (Rh) is the most expensive. A year ago, Rh and Ir...
Back
Top