Isothermal Expansion of a Diatomic Gas

AI Thread Summary
The discussion focuses on calculating the final temperature of a diatomic nitrogen gas undergoing isothermal expansion. The user initially attempts to apply the ideal gas law but struggles with determining the correct number of molecules (N) and the relevance of initial conditions. It is clarified that N refers to the number of particles, which can include molecules or atoms. The user expresses uncertainty about the behavior of diatomic gases and how to incorporate that into their calculations. Ultimately, the conversation highlights the importance of correctly identifying variables and understanding gas behavior in thermodynamic processes.
MaryCate22
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Homework Statement


A 0.300-kg sample of nitrogen gas (diatomic molecules,mN2 = 4.652 × 10^−26 kg) in a chamber fitted with a piston undergoes an isothermal expansion from 0.0500 m^3 to 0.150 m^3 .

If the final pressure is 110 kPa, what is the final temperature?

Homework Equations


PV=N*kB*T where Boltzmann's Constant is kB=1.38*10^-23 J/K

The Attempt at a Solution


Because the process is isothermal, PV = constant and Ti = Tf.
To use the formula, I need N (number of molecules).

0.300/[(4.652*10^-26)(0.5)]=1.29*10^25

Plugging this N into T=PV/NkB I get, T = 92.7 K, which is not the right answer.

I don't think diatomic gasses behave ideally, but I have no idea how to reflect that in the formula. I also do not know how the initial volume and pressures are relevant.
 
Last edited:
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The question is what is the final temperature if the final pressure is 110 kPa. Sorry, I'll edit.
 
Just a thought, am I supposed to use the number of molecules or the number of atoms?
 
MaryCate22 said:
,mN2 = 4.652 × 10^−26 kg

MaryCate22 said:
0.300/[(4.652*10^-26)(0.5)]=

MaryCate22 said:
am I supposed to use the number of molecules or the number of atoms?
 

Well that clears it up. Thank you.
 
N is the number of particles which can be molecules, atoms, ions etc.
 
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