fusefiz said:
This may well be a naive reaction, but it seems to me that the obvious thing to do with the radioactively contaminated water in the turbine buildings is to pump it back into the reactors. Is there something wrong with that action? If/when they are able to re-establish core cooling, perhaps they could then work on dealing with the water contamination (salt, radioactive elements, etc) and leaks. But until then, why not reuse this water for the evaporative cooling?
Joe Neubarth said:
Pump highly radioactive water to an area where it can be heated and release more radioactive delayed neutron precursors or accelerate gamma or Beta emitting dispersal?
Not a good idea.
Pumping contaminated water back to the site of the contamination is not good certainly. Eventually, whatever is leaking out becomes more contaminated, and that means increased dose rate and cumulative dose for those involved.
Assuming the fission has ceased, the delayed neutron precursors, the longest-lived being Br
87 (t
1/2 = ~55 s), are long decayed away.
I'm not sure where they plan to put the contaminated water. Perhaps back in the torus, if it has spare volume. If the contaminated water contains solid fission products, then this would suggest fuel washout, which then suggests some leak path from the primary system, e.g., feedwater system, the reactor water cleanup system, or possibly from somewhere in containment, from the lower levels of the containment, or containment sump and torus.
Ideally the contaminated water would be 'contained' in containment, but that does not appear to be the case, otherwise the contaminated water should be flowing in a closed system. However, with contaminated water in the turbine building, this would seem to be hampering efforts to re-establish a closed system.
Solutions of uranyl ions (e.g., uranyl nitrate hexahydrate) would normally be precipitated in a caustic solution, typically with ammonium hydroxide. The precipitate would be collected, dried and then calcined to an oxide powder. This may be an option, but it requires a special portable chemical process plant. Otherwise the solution has to be dewatered, perhaps by vacuum dehydration in a process similar to the production of freshwater from seawater, which leaves behind a more concentrated solution. The problem then is one of collecting the water - with submersible pumps or vacuum hoses. Given the radioactive contamination in the water, perhaps this operation requires remotely operated vehicles (ROVs).
If there is a leak in containment or the piping of the feedwater and attendant systems, then that has to found and stopped in order to reduce/mitigate further contamination.
I wonder if the boric acid solution is buffered. In PWRs, it is common to buffer with LiOH in western PWRs, and KOH in Russion VVERs. The pH in the coolant is kept near neutral ~7.0, to slightly basic up to about pH = 7.4. Acidic water increases the corrosion of stainless steel and nickel alloys.
FYI - [PDF] Mark I Containment Report
http://www.nei.org/filefolder/Report_-_BWR_Mark_I_Containment_03192011_2.pdf