Making a 50% solution from Liquid Citric Acid

AI Thread Summary
To create a 50% solution of citric acid, it's essential to clarify the concentration of the liquid citric acid in hand, as the label indicating "100% liquid Citric Acid" alongside "Citric Acid and Water" suggests it is not purely citric acid. The discussion highlights the confusion surrounding the measurement of concentration, emphasizing the need to specify whether dilution is by volume or mass. Typically, a 100% citric acid is solid, and a truly concentrated liquid solution would not remain stable at lower temperatures. The solubility of citric acid in water is noted, with a common solution being around 66% w/w at 20°C. Therefore, careful attention to the actual concentration and the method of dilution is crucial for achieving the desired 50% solution.
Robert Brott
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I have a bottle of !00% liquid Citric Acid with the label showing Citric Acid and Water as contents. I need a 50% solution of the acid. Do I dilute this with water 50-50?
 
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Robert Brott said:
!00% liquid Citric Acid with the label showing Citric Acid and (?) Water

Little tough to conceive of a 2 component mixture with one component being 100%; check the label a little more closely. Is it liquid? If so, it is definitely not 100%.

"50:50?" By volume? By mass? Mole fraction? Usually, percentages indicate mass. If you're playing with citric acid, you're in an area where a lot of the exceptions to the "usual" rule occur, often without rhyme or reason. Check your procedure that requires "50%" for details.
 
100% citric acid is solid. It is well soluble, 148 g per 100 g of water at 20°C, such solution would be around 66% w/w. I doubt the one you have is that concentrated, as it would not survive cooling without the acid crashing out from the solution (and below 20°C is quite normal in many places).
 
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