Understanding the Distinctions Between MOFs, COFs, and POPs: A Brief Overview

In summary, Metal Organic Frameworks (MOFs), Covalent Organic Polymers (COFs), and Porous Organic Polymers (POPs) all have different bonding structures. MOFs have metal ions linked by coordination bonds, while COFs and POPs have covalent bonds. In terms of periodicity and structure, MOFs and COFs are distinguishable from POPs. COFs are a crystalline version of POPs, while MOFs are a coordination compound version. POPs are generally considered amorphous. All three materials can have micro- or mesoporous structures.
  • #1
KarolinaPL
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What are the differences between 1) Metal Organic Frameworks (MOFs), 2) Covalent Organic Polymers (COFs) and 3) Porous Organic Polymers (POPs)?? 2 are the same like 1, but there is no coordination bond just covalent bonds? 3 there is no metal atom? how to distinguish between such a similar species?
 
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  • #2
The given three examples have some difference depending on how you classify them.

If you are talking purely in terms of bonding structure, then 1) can be distinguished from 2) and 3). MOFs are composed of metal ion that links organic ligands by coordination bonds. COFs and POPs are composed of covalent bonds.

In terms of periodicity and its well-defined structure, 1) and 2) can be distinguished from 3). In a strict definition (one that is commonly used), COFs are crystalline, well-defined version of POPs, and MOFs are coordination compound version of POPs, since POPs are generally considered amorphous. In a broad sense, COFs are part of POPs.
 
  • #3
So...

1) MOFs (inorganic-organic hydrids which consist of metal/metal clusters nodes and organic ligand as linkers, can be crystalline, amorphous, micro- or mesoporous),
2) crystalline COPs (extended organic structures where building blocks are linked by strong covalent bonds, they are made entirely from light elements (H, B, C, N, and O), micro- or mesoporous),
3) amorphous POPs (a class of highly crosslinked polymers possessing (microporous or porous)) ?

THANK YOU! :smile:
 

1. What are metal organic frameworks (MOFs)?

Metal organic frameworks (MOFs) are a class of highly porous materials composed of metal nodes connected by organic linkers. They have a crystalline structure and a large surface area, making them useful for a variety of applications such as gas storage, catalysis, and drug delivery.

2. How are MOFs synthesized?

MOFs are typically synthesized using solvothermal or hydrothermal methods, where metal salts and organic linkers are mixed in a solvent and heated under high pressure. Other methods such as microwave-assisted synthesis and mechanochemical synthesis have also been developed.

3. What properties make MOFs useful for gas storage?

MOFs have a high porosity and surface area, which allows them to adsorb large amounts of gas molecules. They also have tunable pore sizes and surface chemistries, making it possible to design MOFs with specific gas adsorption properties.

4. What are some potential applications of MOFs?

Aside from gas storage, MOFs have potential applications in catalysis, drug delivery, and sensing. They can also be used for water purification, as the porous structure can trap and remove pollutants from water.

5. Are there any challenges in using MOFs?

One challenge in using MOFs is their stability. Some MOFs may degrade in the presence of water or other solvents, limiting their applications. Additionally, the synthesis of MOFs can be time-consuming and expensive, and not all combinations of metals and organic linkers result in stable MOFs.

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