To find the moles of solute particles in 5.07 mL of 0.688 M Na3PO4, the calculation must consider osmolarity, which accounts for all dissociated ions. The initial calculation yielded 3.49E-3 moles of solute, but this only reflects the molarity of the compound, not the total particle concentration. Since Na3PO4 dissociates into four particles (three Na+ ions and one PO4^3- ion), the correct approach involves multiplying the molarity by four, resulting in 1.40E-2 moles of solute particles. However, adjustments for the behavior of the ions in solution suggest a more accurate total concentration of approximately 2.804 M, leading to a revised mole count of about 14.2E-3. Understanding the distinction between moles of solute and moles of solute particles is crucial for accurate calculations.