I agree the problem seems to suggest you should imagine the temperature stays constant, but that last solution has a lot of problems. The equation of hydrostatic equilibrium (this one is worth committing to memory) says dP/dz = -rho*g and at constant T this says dP/dr = -P/H*(R/r)2), where H is a constant and gets called the "scale height". You can see what it has to be-- H=kT/mg, where m is the mean mass per particle and g is at the surface of the Earth, where r=R. We can redefine a new hight variable, say z=r/R, and get dP/dz = -P*R/H*(1/z)2). That's still not simple enough, so define y = R/H*(1 - 1/z), such that y goes from 0 to H/R. Now we have dP/dy =-P. That has a simple solution-- P/Po = e-y, where y separates P and Po. (Most likely on the scale of 9.6 km, they want you to approximate this with y ~ h/H, where h is the height above the surface, but I give you the full solution as if the constant T could really be continued arbitrarily out into space.)
Since you know P=25, and you want to infer Po at sea level, you need to know the value of y at 9600 km. That requires knowing R and H, so that you can find y=R/H*[1-R/(R+9600)], which will be quite close to 9600/H (that's the usual way people talk about the "number of scale heights above the surface"). So you don't really need to know R, but you'll need to calculate H. Apparently, the problem does need you to know what the T is (and what mg is also, remember m is for a mix of 80% N2 and 20% O2). Note also the curious aspect of this solution-- since y only goes up to R/H, not infinity, there is a finite pressure at infinite r, equal to Poe-R/H. When considered for the Sun, this is related to why there is a solar wind. For Earth, e-R/H is vastly small, and so escape of Earth's atmosphere depends more on things like ozone heating and interactions with the solar wind.