In thermodynamics, total entropy is conserved in reversible processes, while system entropy remains constant in reversible processes without heat flow. For an ideal gas, enthalpy can be expressed as H = nc_PT + H_0, leading to the equation ΔH = nCpΔT, applicable even when pressure is not constant. A reversible process is an idealized scenario where no gradients in temperature or pressure exist, making calculations simpler by assuming zero entropy generation. This idealization is not realizable in practice, as real processes involve energy transfer through differences in temperature and pressure. Understanding these concepts is crucial for analyzing various thermodynamic processes.