Gauss's Law for magnetism is fundamentally tied to the non-existence of magnetic monopoles, meaning that if monopoles were discovered, the equations governing magnetism would need to be revised. The discussion highlights that while Gauss's Law for electric fields can be rigorously derived from Coulomb's Law, a similar formal proof for Gauss's Law for magnetism is lacking due to the absence of magnetic charges. The divergence theorem of vector calculus is mentioned as a mathematical basis for understanding why the magnetic field's divergence is zero in the absence of magnetic monopoles. Additionally, the conversation emphasizes that classical electrodynamics, including Maxwell's equations, is primarily derived from empirical observations rather than formal proofs. Ultimately, the relationship between electric and magnetic laws remains a topic of exploration, particularly in the context of building a comprehensive understanding of classical electromagnetism.