Well, if you're familiar with the unit circle definition of the trigonometric functions, the sine and cosine of them aren't altogether that difficult to calculate.
Definition: We define the trigonometric functions as following: sin(theta) = y/r and cos(theta) = x/r where x and y refer to specific points on the unit circle and r is the radius. All other trig. functions can be defined as variants of these.
We define the unit circle as following: x^2 + y^2 = 1.
Hence, suppose we wish to find the sin(pi/2). Examining the unit circle - in standard position - we find an arc of pi/2 occurs at the point (0,1); therefore, by our definition of trig. functions sin(pi/2) = 1. Note that this really only works well for the arcs pi/2, pi/4, and 0. Does that make sense?
Edit: Now, here's a proof for the values of pi/3 and pi/6. Consider a 30-60-90 triangle. We may claim that the area of of 30-60-90 triangle is half that of an equilateral triangle. If an equilateral triangle is of side length 1 (as is the case in the unit circle) it is then immediately obivous that the side adjacent the 60 degree angle measure is 1/2. Therefore, cos(60) = cos(pi/3) = 1/2. Similar logic will yield the values for sin(pi/3) and all the other related values.
Sorry if the above doesn't make sense. Try drawing it out, it should help.