Question on adiabatic expansion

AI Thread Summary
The discussion revolves around a problem involving the adiabatic expansion of an ideal gas, where the user is struggling to calculate the work done (W) and the change in internal energy (dEint) after determining the initial and final pressures and temperatures. The user initially misapplies the formula for work in an adiabatic process, thinking it is W = nRdT, which leads to incorrect results. Participants clarify that the correct approach involves using the relationship PV^γ = constant and integrating the differential work equation dW = PdV. The user acknowledges their confusion and fatigue, ultimately deciding to seek clarification from their teacher the next day.
tristan_fc
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I've been struggling with this problem for an hour or so now, and can't seem to find the right answer. Perhaps someone here can help? I would be very grateful. ;)

Two moles of an ideal gas ( = 1.40) expands slowly and adiabatically from a pressure of 5.09 atm and a volume of 12.7 L to a final volume of 30.0 L.

I had to find this stuff first, and I know I have all of it right.

final pressure: 1.528
initial temp: 393.5K
final temp: 279

Find Q, W, dEint.

I know Q is 0, and I know that Work and change in internal Energy are the opposite of each other, but I can't seem to find the right value for them. I thought work = nRdT, which in this case is:

2*.08214*(393.5-279)=1902.9

However, that answer is wrong according to webassign. There is also a problem in my textbook that is the same, except with different numbers, and i tried that one and got it wrong too. Anyone know what I'm doing wrong? Your help is greatly appreciated. :)
 
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Formula for work done in adiabatic process is wrong
 
so what is the proper formula? The textbook goes through a proof of why PV^y is constanst, but doesn't really go any further from that... I'm guessing that's somehow incorperated into the formula...
 
Write the differential equation for for work done for gas
i.e
dW=PdV

Note PV^\gamma= K

substitute P from above in workdone equation and calculate the work done by taking limits from V1 to v2
 
eh... P from above what? P is not constant.
 
Refining it
dW=kV^-^\gamma dV

I hope u will got it now
 
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Okay, I thought maybe that's what you meant, but I'm sorry I don't see what good that does if I don't know what k is. Maybe I'm just slow tonight as I only got about 4 hours of sleep last night and am rather tired... Sorry. [zz)]

Ah well, it was due at midnight. So I'll just ask my teacher how to do it tomorrow...
 
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k is a constant which is given by

PV^\gamma= k

P_iV_i^\gamma = P_fV_f^\gamma= k
 
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Oh duh. Sorry, I guess I was just really tired last night. ;) Anyway thanks for the help.
 
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