Rigid Walled Box (Quantum Mechanics)

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SUMMARY

The discussion focuses on the quantum mechanics problem involving a rigid-walled box divided into three sections, each containing one particle in its ground state. The total energy of the system as a function of the interior wall position, x, is derived using the formula En=(n²π²ħ²)/(2mL²). The minimum energy occurs when x equals L/3, resulting in Emin=(27π²ħ²)/(8mL²). The participants clarify the configuration of the box and the implications for energy calculations.

PREREQUISITES
  • Understanding of Schrödinger's Equation
  • Familiarity with quantum mechanics concepts such as energy levels and wave functions
  • Knowledge of the rigid-walled box model in quantum physics
  • Basic proficiency in mathematical inequalities and their applications
NEXT STEPS
  • Study the implications of boundary conditions in quantum mechanics
  • Learn about the derivation and application of Schrödinger's Equation in various systems
  • Explore the concept of energy quantization in multi-particle systems
  • Investigate the use of inequalities in quantum mechanics for energy minimization
USEFUL FOR

Undergraduate students in physics, particularly those studying quantum mechanics, as well as educators and researchers looking to deepen their understanding of particle systems in confined spaces.

robotpie3000
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Homework Statement



I have just started my undergraduate quantum mechanics lectures and I am currently stuck in this question:

A rigid-walled box that extends from -L to L is divided into three sections by rigid
interior walls at -x to +x, where x<L . Each section contains one particle in its ground
state.
(a) What is the total energy of the system as a function of x?
(b) Sketch E(x) versus x.
(c) At what value of x is E(x) a minimum?

Homework Equations



En=(n2π2ħ2)/(2mL2)
EΨ(x,t) = iħ(∂Ψ(x,t))/(∂t)

The Attempt at a Solution


[/B]
a) The energy of the system as a function of x should obey Schrödinger's Equation, so EΨ(x,t) = iħ(∂Ψ(x,t))/(∂t), but I'm not sure how to find a solution to Ψ(x,t) that may help me move forward.

b) After reading my textbook for a while, I have decided to draw the total energy as a straight line parallel to the horizontal x axis.

c) I was thinking since there are 3 particles within the rigid walled box, the minimum energy of the system would be E3=(9π2ħ2)/(2m(2L2)), since the length of the box is 2L.

Help is much appreciated!
 
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robotpie3000 said:
there are 3 particles within the rigid walled box

No, you have three rigid walled boxes (bounded by the "rigid interior walls"), each containing one particle.
 
So I've been thinking about this for a while and I think I've found the answer.

There are three regions: [-L, -x],[-x, x] and [x, L]. So the length of each region would be L-x, 2x and L-x respectively. If we let a1=1/(L-x)2, a2=1/(2x)2, and a3=1/(L-x)2, and use the inequality relationship ((a12 + a22 + a32)/n)1/2 ≥ (a1 + a2 + a3)/n, we can show that ([1/(L-x)2] + [1/(2x)2] + [1/(L-x)2])/3 ≥ 9/4L2.

E is a minimum if L-x = 2x, which means x=L/3, and Emin=3*[(π2ħ2)/(2m)]*[27/(4L2)]=(27π2ħ2)/(8mL2).



 

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