Saturated VapourPressure of Steam above Critical Temperature

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SUMMARY

The discussion centers on the saturated vapor pressure of steam above the critical temperature of 374 degrees Celsius. It is established that no saturated vapor pressure exists above this critical temperature, meaning that water cannot condense regardless of pressure. The user initially employed Antoine's Equation for calculations but encountered errors when temperatures exceeded 374 degrees Celsius. Resources such as the ASME Steam Tables and the NIST publications are referenced for further understanding of steam properties.

PREREQUISITES
  • Understanding of Antoine's Equation for vapor pressure calculations
  • Familiarity with the concept of critical temperature in thermodynamics
  • Knowledge of steam properties and phase transitions
  • Experience with using steam tables and Mollier Charts
NEXT STEPS
  • Research the implications of critical temperature on phase changes in fluids
  • Study the ASME Steam Tables for detailed steam property data
  • Explore the NIST publications on steam properties for industrial applications
  • Learn about alternative methods for calculating vapor pressure in supercritical fluids
USEFUL FOR

This discussion is beneficial for engineers, thermodynamicists, and researchers involved in fluid dynamics, particularly those working with steam and gas turbine systems.

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Hello all,

I am not sure my question will totally make sense for those of you who now this topic well but as I am new to it I hope I can be forgiven.

My problem is to work out how much water will condensate as a stream of moist air is expanded through a turbine.

So far I was using Antoine's Equation (https://en.wikipedia.org/wiki/Antoine_equation) to determine how much water could be held in my gas stream at the turbine outlet Pressure and Temperature.

I however have cases where my outlet Temperature is greater than 374 degrees C, and my code returns an error. I have been looking for equations or tables providing the saturated vapour pressure for temperatures above 374 C but I couldn't find anything.

Any help or comment would be welcome.
 
Science news on Phys.org
There is no such thing as saturated vapor pressure above the critical temperature. No amount of pressure can cause a substance to condense if the temperature exceeds the critical temperature.
 

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