Setup Thermodynamic Cycle for Enthalpy of Hydration of Mg2+ Ions

AI Thread Summary
To determine the enthalpy of hydration of Mg2+ ions, a thermodynamic cycle must be set up using provided enthalpies, including sublimation of Mg, ionization energies, dissociation enthalpy of Cl2, electron gain enthalpy of Cl, and the enthalpy of solution of MgCl2(s). The solvation enthalpy is crucial, transitioning from solid to liquid, alongside the enthalpy of Cl- in solution. The total change in enthalpy for the cycle should equal zero, but clarification is needed on how to calculate the differences between MgCl2(s) and the gas phases. Participants express uncertainty about the relationships of the processes to Mg2+ hydration and seek guidance on completing the cycle. Understanding these relationships is essential for accurately determining the enthalpy of hydration.
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Homework Statement


Set up thermodynamic cycle for determining the enthalpy of hydration of Mg2+ ions
The following enthalpies are given
Sublimation of Mg
ionization energies of Mg
dissociation enthalpy of Cl2
electron gain enthalpy of Cl
enthalpy of solution of MgCl2(s)
enhalpy of hydration of Cl-


Homework Equations





The Attempt at a Solution




any hints how to set up the cycle?
 
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Is any of the processes mentioned related to Mg2+ hydration?
 
Borek said:
Is any of the processes mentioned related to Mg2+ hydration?
yeah, the solvation enthalpy, from solid to liquid, then the enthalpy of Cl- in the solution. The change of the enthalpy in the cycle should be 0, but how to find the difference in the MgCl2(s) and the gas phases?
 
Sorry, no idea what I was thinking :frown: Looks like there is something missing here.
 
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