The "biggest circle on a sphere" is simply as "great circle" and there are an infinite number of them. The simplest thing to do is to take the great circle that is parallel to the xy-plane, given by x= 1+ cos(t), y= 1+ sin(t), z= 1.
Then dx= -sin(t)dt, dy= cos(t)dt, and dz= 0. yz= 1+ sin(t), xz= 1+ cos(t), and xy= 1+ sin(t)+ cos(t)+ sin(t)cos(t) but since that will be multiplied by dz= 0, it doesn't matter. The integral will be
\int_{t=0}^{2\pi} [-(1+ sin(t))sin(t)+ (1+ cos(t))cos(t)]dt
The identity cos^2(t)- sin^2(t)= cos(2t) might be helpful.
I said there are an infinite number of great circles but it should be evident from the symmetry that they all give the same integral.