Temperature change (first law of thermodynamics)

AI Thread Summary
The discussion centers on the application of the first law of thermodynamics to temperature changes, particularly in the context of diurnal temperature evolution. It highlights that while the rate of heat flow (dQ/dt) can be negative during certain times of the day, the overall energy (Q) can still be positive, allowing for continued temperature increases. The distinction between Eulerian temperature changes and Lagrangian energy flux density is emphasized, noting that temperature is measured at a fixed position while energy flows through the air. This understanding clarifies the relationship between heat flow and temperature changes throughout the day. The conversation concludes with the recognition that both concepts are observed from a stationary perspective on Earth's surface.
jones123
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Hi,

From the first law of thermodynamics it follows:

Cp * (δT/δt) = (δQ/δt)
where Cp = specific heat capacity, T = temperature, Q = heat, t = time

From this formula, you would derive that temperature keeps on increasing as long as dQ/dt > 0. But if you, for example, look at the idealized diurnal evolution of air temperature, it can be seen that the temperature keeps on increasing until its maximum value, despite the fact that there is net heat loss (dQ/dt < 0 for example between noon and 4h where the area between both curves becomes smaller)...

It seems that on the figure here the temperature keeps on rising as long as the value of Q itself > 0 but that doesn't necessarily mean that dQ/dt has to be > 0, right? Is my reasoning wrong or how can this correctly be explained with formulas?

Thanks already!

DailyT.jpg
 
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The sun doesn't heat the air, it heats the ground.
 
jones123 said:
Hi,

From the first law of thermodynamics it follows:

Cp * (δT/δt) = (δQ/δt)
where Cp = specific heat capacity, T = temperature, Q = heat, t = time

From this formula, you would derive that temperature keeps on increasing as long as dQ/dt > 0. But if you, for example, look at the idealized diurnal evolution of air temperature, it can be seen that the temperature keeps on increasing until its maximum value, despite the fact that there is net heat loss (dQ/dt < 0 for example between noon and 4h where the area between both curves becomes smaller)...

It seems that on the figure here the temperature keeps on rising as long as the value of Q itself > 0 but that doesn't necessarily mean that dQ/dt has to be > 0, right? Is my reasoning wrong or how can this correctly be explained with formulas?

Thanks already!

View attachment 205308
dQ/dt is the current rate of solar heat flow. So throughout the day, current rate of solar heat flow is positive. The graph says Energy Rate, not cumulative amount of energy.
 
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Chestermiller said:
dQ/dt is the current rate of solar heat flow. So throughout the day, current rate of solar heat flow is positive. The graph says Energy Rate, not cumulative amount of energy.
Oh I get it,

it's just that the temperature change is Eulerian (a local change at a fixed position) whereas the energy flux density is Lagrangian (it crosses the air on its path while having a negative or positive value).
 
jones123 said:
Oh I get it,

it's just that the temperature change is Eulerian (a local change at a fixed position) whereas the energy flux density is Lagrangian (it crosses the air on its path while having a negative or positive value).
Both are as reckoned by a "stationary" observer on the surface of the earth.
 
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