Calculating the temperature of air escaping from a tire involves understanding adiabatic expansion, represented by the equation T_i V_i^{\gamma-1} = T_f V_f^{\gamma-1}. The initial state (T_i, V_i) refers to the conditions of the air inside the tire, while the final state (T_f) pertains to the air exiting. The volume of escaping air (V_f) can be determined based on the ambient pressure, as it expands to 1 atm. The discussion also touches on how the velocity of the escaping air and the size of the nozzle can affect temperature changes, including potential temperature inversions. Understanding these factors is crucial for accurate calculations.