The difference between structural unit and repeating unit?

In summary, the difference between a structural unit and a repeating unit is that a structural unit is a substructure derived directly from the inputs, while a repeating unit is the unit that is repeated throughout the polymer. Polyethylene terephthalate has two structural units, but only one repeating unit. This can be seen in the examples of polyethylene terephthalate, which has a repeating unit of [-O-CH2-CH2-O-CO-Ph-CO-], but is built from two distinct structural units, and polyethylene, which has a repeating unit of [-CH2-] but a structural unit of [-CH2-CH2-] because it is derived from ethylene.
  • #1
royzizzle
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Homework Statement



The difference between structural unit and repeating unit

Homework Equations





The Attempt at a Solution



http://en.wikipedia.org/wiki/Structural_unit

wikipedia gives an example with polyethylene terephthalate but I can't figure it out based on the slight difference
 
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Polyethylene teraphthalate has two structural units but only has one repeating unit.

Structural units are substructures that are derived directly from the inputs.

If you call the repeating unit [-R-], then you can write a polymer as -[-R-]-n.

So while polyethylene teraphthalate has the repeating unit [-O-CH2-CH2-O-CO-Ph-CO-], it's built from two distinct inputs and each of those is a different structural unit.

To take another example, polyethylene, which once was also called polymethylene, -[-CH2-]-n, has the repeating unit [-CH2-] but has the structural unit [-CH2-CH2-] because it is derived from ethylene, not methyl radical.
 
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1. What is the difference between a structural unit and a repeating unit?

Structural units refer to the individual components that make up a larger structure, while repeating units refer to the smallest unit that is repeated to create the overall structure. In other words, structural units make up repeating units, which in turn make up the overall structure.

2. How are structural units and repeating units related?

Structural units are related to repeating units in that they are the building blocks for the repeating units. Without structural units, the repeating units could not exist and therefore, the overall structure would not exist.

3. Can you give an example of a structural unit and a repeating unit?

An example of a structural unit could be a carbon atom, while a repeating unit for a polymer could be a monomer made up of multiple carbon atoms. Another example could be a brick as a structural unit and a wall made up of multiple bricks as a repeating unit.

4. How do structural units and repeating units contribute to the properties of a material?

The arrangement and type of structural units and repeating units in a material determine its physical and chemical properties. For example, a polymer made up of repeating units with strong covalent bonds will result in a strong and durable material, while a polymer with weak intermolecular forces between repeating units will result in a more flexible material.

5. Can structural units and repeating units be different in size?

Yes, structural units and repeating units can differ in size. Structural units can be small molecules, atoms, or even larger complexes, while repeating units can be made up of multiple structural units. For example, a protein made up of amino acids as structural units can have repeating units of multiple amino acids to form a larger protein structure.

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