Thermal Expansion Ethanol Problem

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Homework Help Overview

The problem involves thermal expansion and equilibrium between ethanol and a glass cylinder, focusing on the final temperature of the ethanol and the volume that overflows as the ethanol warms. The context includes specific heat and coefficients of volume expansion for both the ethanol and the glass cylinder.

Discussion Character

  • Exploratory, Assumption checking, Problem interpretation

Approaches and Questions Raised

  • Participants discuss the necessity of knowing the initial volume of the cylinder to determine overflow, questioning the problem's setup and assumptions regarding the expansion of both the ethanol and the glass cylinder.

Discussion Status

Some participants express skepticism about the problem's clarity and assumptions, particularly regarding the contraction of the cylinder and how it relates to the overflow of ethanol. There is a recognition that assumptions may need to be made about the cylinder's capacity.

Contextual Notes

Participants note the lack of information about the cylinder's volume and shape, which complicates the calculations for overflow and thermal expansion. The problem's wording is also critiqued for potentially misleading interpretations.

Fizzicist
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Homework Statement



You pour 108 cm^3 of ethanol, at a temperature of -10.0 degrees C, into a graduated cylinder initially at 20.0 degrees C, filling it to the very top. The cylinder is made of glass with a specific heat of 840 J/(kg *K) and a coefficient of volume expansion of 1.2 *10^-5 K^-1; its mass is 0.110 kg. The mass of the ethanol is 0.0873 kg.

A. What will be the final temperature of the ethanol, once thermal equilibrium is reached?

(Answer: -.892 degrees C)

B. How much ethanol will overflow the cylinder before thermal equilibrium is reached?

Homework Equations



Equation for volumetric expansion:

[tex]\Delta[/tex]V = [tex]\beta[/tex] V0 ([tex]\Delta[/tex]T)

The Attempt at a Solution



I honestly think this question (part B) is flawed. How could you solve this without knowing V0, the initial volume of the cylinder? And even if you did know the volume of the cylinder, you still wouldn't be able to determine the volume capacity it is able to hold (the ratio of volume capacity to volume of the cylinder varies). Is this even possible?
 
Last edited:
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You can do part 'a' easily.

B, You can't know how much it will overflow without knowing the volume of the cylinder.
But I think you are meant to assume that 108cc of cold ethanol will fill the cylinder to the top and it overflows when it warms - so just work out how much the ethanol expands
 
B, You can't know how much it will overflow without knowing the volume of the cylinder.
But I think you are meant to assume that 108cc of cold ethanol will fill the cylinder to the top and it overflows when it warms - so just work out how much the ethanol expands


Yeah. That seems reasonable...

I didn't like the way this question was asked. It made it sound as if you were supposed account for the contraction of the cylinder because it gave you the coefficient of volumetric expansion for the glass.
 
Yes - especially because you would need to know the shape of the cylinder!
The volume expansion of the glass isn't the volume expansion of the cylinder.
If you had a thin-walled spherical container and the glass expanded would the volume inside get bigger or would the wall just get thicker and expand outward?
 
How did you find part A?

Fizzicist said:
Yeah. That seems reasonable...

I didn't like the way this question was asked. It made it sound as if you were supposed account for the contraction of the cylinder because it gave you the coefficient of volumetric expansion for the glass.

?

You are supposed to account for the contraction of the cylinder.
 
?

You are supposed to account for the contraction of the cylinder.


TY, but I figured this out about a year ago.
 

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