Thermal Expansion for an Ideal Gas

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SUMMARY

The discussion focuses on proving that the coefficient of volume expansion for an ideal gas is the reciprocal of the Kelvin temperature when expansion occurs at constant pressure. The relationship is derived from the ideal gas law, expressed as pv=nRT. The coefficient of thermal expansion at constant pressure is defined as αV=1/V(∂V/∂T)p, leading to an inverse temperature dependence when substituting V(T)=nRT/p.

PREREQUISITES
  • Understanding of the ideal gas law (pv=nRT)
  • Knowledge of thermal expansion coefficients
  • Familiarity with calculus, specifically partial derivatives
  • Basic concepts of thermodynamics
NEXT STEPS
  • Study the derivation of thermal expansion coefficients for various states of matter
  • Explore the implications of the ideal gas law in real-world applications
  • Learn about the differences in thermal expansion between solids and gases
  • Investigate the behavior of non-ideal gases under varying temperature and pressure conditions
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Students studying thermodynamics, physics educators, and professionals in engineering fields focusing on gas behavior and thermal properties.

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Homework Statement



The pressure p , volume V, number of moles n, and Kelvin temperature K of an ideal gas are related by the equation pv=nRT , where R is a constant. Prove that the coefficient of volume expansion for an ideal gas is equal to the reciprocal of the Kelvin temperature if the expansion occurs at constant pressure.

Homework Equations


Compare the coefficients of volume expansion of copper and air at a temperature of 20 C. Assume that air may be treated as an ideal gas and that the pressure remains constant.


The Attempt at a Solution


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The coefficient of thermal expansion at constant pressure is given by
$$\alpha_V=\frac{1}{V}\left(\frac{\partial V}{\partial T}\right)_p$$
By calculating this quantity for ##V(T)=\frac{nRT}{p}##, you can show an inverse temperature dependence.
 

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