Thermodynamics/Statistical Mechanics Probability Questions

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Homework Help Overview

The discussion revolves around probability questions related to thermodynamics and statistical mechanics, specifically focusing on ideal gas behavior and molecular distributions within a given volume.

Discussion Character

  • Exploratory, Conceptual clarification, Problem interpretation

Approaches and Questions Raised

  • The original poster attempts to determine whether the equipartition theorem is necessary for solving the probability questions presented. Some participants suggest that the problems can be approached as statistical problems without needing to apply the theorem directly.

Discussion Status

The discussion is ongoing, with participants sharing their thoughts on the relevance of the equipartition theorem. There is a general agreement that the problems are fundamentally about probability rather than requiring specific thermodynamic principles.

Contextual Notes

The original poster notes missing class material related to the equipartition theorem, which may affect their understanding of the problems. Additionally, there is mention of a textbook that was not assigned for the course, which could imply constraints on available resources for the original poster.

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Homework Statement


On this problem set, there are multiple questions regarding the probability of events:

1. Consider a box of volume V containing N molecules. Assume that the molecules in the box are free of all interactions, that is, that the equation of state is that of an ideal gas.
(a) What is the probability of finding all the molecules in a portion of the container having a volume
V/2?
(b) If N=1023, what is the numerical value of this probability?

2. A volume V contains NA molecules of type A and NB molecules of type B. A valve is opened and M molecules flow out. What is the probability that among the M molecules there are mA of species A and mB of species B?

3. Suppose that a volume V is subdivided into M sub-volumes. Let there be N molecules in V. What is the probability that some one sub-volume will contain N’ molecules?

Homework Equations



Equipartition theorem

The Attempt at a Solution



I missed class, and I know the material I missed was the equipartition theorem. I am unsure if these problems require application of the equipartition theorem, or if I can just logic at them. Conveniently, this lecture was taken from a textbook that was not assigned for the course. Thoughts?
 
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I don't really think an understanding of equipartition theorem is required further than what Wikipedia can provide. Just consider it a big statistical problem (you have no interactions) and should be okay.
 
They don't. They're just probability problems.
 
Cool, thanks guys :)
 

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