forcefield said:
How can that be ? Wouldn't the force between the particles always bring them together, no matter what the distance between them is ?
Yeah, that's a good point. The hydrogen atom could just be in a very high energy state, like n=1000, or n=some even larger number. So I guess in principle even if the electron and proton are very far away from each other, they still make up a hydrogen atom. I guess that when they are very far apart, you can say that they are approximately free particles. For example, for principle quantum number 'n' being very large, the difference between adjacent energy levels is very small, so you almost have a continuum of different energy levels, like you would have in 'truly free' particles.
edit: and I forgot to say, yes classically there would be a force which pulls them together. But in quantum mechanics, it's not so simple. In a hydrogen atom, there is spontaneous emission of a photon, to send the atom to a lower energy level. But I am not certain about what happens in the limit of electron and proton being very far from each other. I think that as long as we can assume that the wavelength of the emitted photon is large compared to the 'average' distance between proton and electron, then in the limit of large quantum number 'n', the probability of spontaneous emission per unit time tends to zero. (And I have been talking about dipole interaction here, I probably did not make that clear). But anyway, this is reassuring, since I would expect that when the proton and electron get very far from each other, they are almost free and are unlikely to emit any radiation due to dipole interaction, since they are hardly a hydrogen atom anymore.
edit again: The assumption that the wavelength of the emitted photon is large compared to the 'average' distance between electron and proton allows us to make a standard simplification of the equations (I think). But even if we can't make this assumption, I'm pretty sure that we still won't see much dipole radiation being emitted by the hydrogen atom when it is in a very large 'n' quantum number state.
final edit: yeah, so (I think) in quantum mechanics, we get a similar answer as we do for classical mechanics. i.e. if the electron and proton are very far away from each other, they won't get 'pulled towards each other' as much. (In a very loose sense of the word). And I would guess that in quantum mechanics, this decrease of interaction with distance is even more pronounced than it is for classical mechanics. (In classical mechanics, the force is 1/r^2). But in quantum mechanics (with field theory), I think maybe it will be even steeper than this, due to screening by virtual particles. Yes, this is a very qualitative answer, sorry for that. I suppose that just shows that I'm not 100% sure of what I'm talking about.