Time taken for two substances to reach equilibrium (equation?)

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The discussion centers on the relationship between the time it takes for a system to reach thermal equilibrium and the volumes of the beakers involved. An experiment is described where a smaller beaker at 25°C is placed inside a larger one at 100°C, taking 7 minutes to equilibrate. A question arises about whether reducing the inner beaker's volume to one-fourth of the outer beaker would halve the time to reach equilibrium. The conversation also touches on the concept of equilibrium in chemical reactions, specifically referencing the time constant for a simple reaction A <-> B, defined as 1/(k1 + k2), where k1 and k2 are the forward and reverse rate constants, respectively. Clarification is sought on how this time constant is applied and whether the rates pertain to the time taken to reach equilibrium. The discussion indicates a need for a deeper understanding of the principles governing thermal and chemical equilibrium.
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I was wondering is there a formula that relates to the time it takes for a system to reach equilibrium? For example in an experiment I used one beaker at 25C inside another at 100C. The volume of the inner beakers was 1/2 that of the outer and with this combiation it took 7minutes for both beakers to reach the same temperature. If the volume of the inner beaker were changed to 1/4 of the outer beaker (starting at the same temperatures) would it take half the time to reach equilibrium as the previous example?
 
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This is more of a physics question. For a simple A <-> B chemical reaction with forward rate k1 and reverse rate constant k2 the time constant for reaching equlibrium is 1/(k1 + k2) if I remember correctly.
 
Nemus said:
This is more of a physics question. For a simple A <-> B chemical reaction with forward rate k1 and reverse rate constant k2 the time constant for reaching equlibrium is 1/(k1 + k2) if I remember correctly.

The time constant how is this then used? Forward and Reverse rate - are these the rates at which the equation takes to reach equilibrium? e.g. Graph attached?

EDIT: Ignore the writing at the bottom of the graph - I know it's a pointless statement
 

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